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Yasuna Kawasaki

Publications and source records attributed to Yasuna Kawasaki.

9 recordsLinked to original sources

Fabrication of binary FeSe superconducting wires by novel diffusion process

We report successful fabrication of multi- and mono-core FeSe wires with high transport critical current density Jc using a simple in-situ Fe-diffusion process based on the powder-in-tube (Fe-diffusion PIT) method. The seven-core wire showed transport Jc of as high as 1027 A/cm2 at 4.2 K. The superconducting transition temperature Tczero was observed at 10.5 K in the wire-samples, which is about 2 K higher than that of bulk FeSe. The Fe-diffusion PIT method is suitable for fabricating multi-core wires of the binary FeSe superconductors with superior properties.

cond-mat.supr-con↗

Electrodeposition as a new route to synthesize superconducting FeSe

We have successfully synthesized FeSe films by the electrochemical deposition in the electrolyte containing FeCl_{2}\cdot4H_{2}O, SeO_{2} and Na_{2}SO_{4}. The composition ratio of Fe and Se was controlled by the synthesis voltage and pH value. The FeSe film with the composition ratio of Fe : Se = 1 : 1 is fabricated at a voltage of -0.9 V and pH 2.1 in our electrochemical deposition. This sample has a highly crystalline tetragonal FeSe structure and exhibits a superconducting transition at 8.1 K, comparable to FeSe synthesized by other methods.

cond-mat.supr-con↗

One-step synthesis of KxFe2-ySe2 single crystals for high critical current density

We have established a simple process that allows for the one-step synthesis of KxFe2-ySe2 single crystals, which exhibit high critical current density Jc. The post annealing and quenching technique has improved the homogeneity of as-grown crystals, resulting in full shielding of the external magnetic field. The quenched crystals show a superconducting transition at Tconset = 32.9 K and Tczero = 32.1 K. The upper critical fields μ_{0}Hc2(0) for H//ab and H//c are estimated to be ~206 and ~50 T, respectively. The critical current densities Jc for H//ab and H//c reach as high as 1.0\times10^{5} and 3.4\times10^{4} A/cm2 at 5 K. Furthermore, Jc exhibits a high field performance and a significantly weak temperature dependence up to 5 T, suggesting strong pinning. These results demonstrate that KxFe2-ySe2 would be a promising candidate material for practical applications.

cond-mat.supr-con↗

Enhancement of superconducting properties in FeSe wires using a quenching technique

Enhancements of superconducting properties were observed in FeSe wires using a quenching technique. Zero resistivity was achieved at about 10 K in quenched wires, which is about 2 K higher than that of polycrystalline FeSe bulk. Furthermore, transport Jc of quenched wires showed three times higher than that of furnace-cooled wires. In contrast, the quenched polycrystalline FeSe bulks did not show the enhancement of Tc. The quenching technique is a greatly promising for fabricating FeSe wires with high Tc and high Jc, and quenched FeSe wires have high potential for superconducting wire applications.

cond-mat.supr-con↗

Transport properties and microstructure of mono- and seven-core wires of FeSe1-xTex superconductor by Fe-diffusion powder-in-tube method

We report the successful fabrication of mono- and seven-core superconducting wires of FeSe1-xTex using an in-situ Fe-diffusion process based on the powder-in-tube (Fe-diffusion PIT) method. The reacted layer in these wires were found to have composite structure with composition nearly FeSe and FeTe for the inner and outer layers, although a single layer of composition FeSe0.5Te0.5 was supposed to be formed. The self-field transport Jc values at 4.2 K were found to be 226.2 A/cm2 and 100.3 A/cm2 respectively for mono- and seven-core wires. The Jc's of mono- and seven-core wires dropped rapidly at low fields and then showed a gradual decrease with increasing magnetic fields. In addition, the seven-core wire showed higher Jc than the mono-core wire under higher magnetic fields, indicating that the seven-core wire of FeSe1-xTex superconductor using Fe-diffusion PIT method is advantageous for the superconducting-wire application under high magnetic fields.

cond-mat.supr-con↗

Electrochemical synthesis of iron-based superconductor FeSe films

The superconducting FeSe films were successfully fabricated using the electrochemical synthesis. The composition ratio of Fe and Se can be controlled by the electric potential and pH value. We found that the FeSe films deposited at the electric potential -1.75 V and pH 2.3 show the superconducting transition at 3.5 K. The establishment of this electrochemical synthesis technique will provide many advantages for application.

cond-mat.supr-con↗

Transport properties of the new Fe-based superconductor KxFe2Se2 (Tc = 33 K)

We synthesized the new Fe-based superconductor K0.8Fe2Se2 single crystals. The obtained single crystal exhibited a sharp superconducting transition, and the onset and zero-resistivity temperature was estimated to be 33 and 31.8 K, respectively. A high upper critical field of 192 T was obtained. Anisotropy of superconductivity of K0.8Fe2Se2 was ~3.6. Both the high upper critical field and comparably low anisotropy are advantageous for the application under high magnetic field.

cond-mat.supr-con↗

Superconductivity in oxygen-annealed FeTe1-xSx single crystal

We investigated the S-doping-driven phase transition from antiferromagnetic to superconducting in FeTe1-xSx single crystals. The partial substitution of Te by S suppresses antiferromagnetism in Fe-square lattice. Superconductivity is induced by oxygen annealing for only FeTe1-xSx in which the long-range magnetic ordering is suppressed. To realize superconductivity in FeTe1-xSx, both S concentration enough to suppress antiferromagnetism and oxygen annealing are required. Anisotropy of superconductivity in oxygen-annealed FeTe0.886S0.114 was estimated to be 1.17.

cond-mat.supr-con↗