arXiv subjects

Zachery A. Enderson

Publications and source records attributed to Zachery A. Enderson.

3 recordsLinked to original sources

arXiv2026

Flat-Band Generation in InAs/GaSb Quantum Wells through Vertically Engineered Heterostructures

Quantum materials constitute a novel category of substances wherein quantum effects and electron-electron (e-e) interactions give rise to unforeseen phenomena on a macroscopic scale. Of particular interest within the realm of quantum materials are flat bands, which promote heavy conduction electrons and enhance e-e correlation effects. While the engineering of such flat bands has been demonstrated in graphene and two-dimensional transition metal dichalcogenides moiré superlattices and in lithography defined semiconductor moiré superlattices, conventional tear-and-stack fabrication methods face challenges due to inevitable twist-angle disorder, strain, and relaxation effects, leading to issues with reproducibility and scalability. Here, we explore the creation and modification of flat bands through vertically engineered III-V semiconductor heterostructures, without the need for twisting. These artificial quantum materials offer a reproducible and scalable means for producing high-quality flat-band materials via molecular beam epitaxy growth. Our investigation includes magnetotransport and infrared magneto-spectroscopy studies of quad-layer InAs/GaSb quantum wells, accompanied by k*p band structure calculations, which illustrate the flattening of bands in vertically designed heterostructures.

cond-mat.mes-hall↗

arXiv2025

Lithography defined semiconductor moires with anomalous in-gap quantum Hall states

Quantum materials and phenomena have attracted great interest for their potential applications in next-generation microelectronics and quantum-information technologies. In one especially interesting class of quantum materials, moire superlattices (MSL) formed by twisted bilayers of 2D materials, a wide range of novel phenomena are observed. However, there exist daunting challenges such as reproducibility and scalability of utilizing 2D MSLs for microelectronics and quantum technologies due to their exfoliate-tear-stack method. Here, we propose lithography defined semiconductor moires superlattices, in which three fundamental parameters, electron-electron interaction, spin-orbit coupling, and band topology, are designable. We experimentally investigate quantum transport properties in a moire specimen made in an InAs quantum well. Strong anomalous in-gap states are observed within the same integer quantum Hall state. Our work opens up new horizons for studying 2D quantum-materials phenomena in semiconductors featuring superior industry-level quality and state-of-the-art technologies, and they may potentially enable new quantum information and microelectronics technologies.

cond-mat.mes-hall↗

arXiv2023

Tailoring on-surface molecular reactions and assembly through hydrogen-modified synthesis: From triarylamine monomer to 2D covalent organic framework

Relative to conventional wet-chemical synthesis techniques, on-surface synthesis of organic networks in ultrahigh vacuum has few control parameters. The molecular deposition rate and substrate temperature are typically the only synthesis variables to be adjusted dynamically. Here we demonstrate that reducing conditions in the vacuum environment can be created and controlled without dedicated sources -- relying only on backfilled hydrogen gas and ion gauge filaments -- and can dramatically influence the Ullmann-like on-surface reaction used for synthesizing two-dimensional covalent organic frameworks (2D COFs). Using tribromo dimethylmethylene-bridged triphenylamine ((Br$_3$)DTPA) as monomer precursors, we find that atomic hydrogen blocks aryl-aryl bond formation. Control of the relative monomer and hydrogen fluxes is used to produce large islands of self-assembled monomers, dimers, or macrocycle hexamers. On-surface synthesis of these oligomers, from a single precursor, circumvents potential challenges with protracted wet-chemical synthesis or low precursor volatility for large molecules. Using scanning tunneling microscopy and spectroscopy (STM/STS), we show that changes in the electronic states through this oligomer sequence provide an insightful view of the 2D-COF (synthesized in the absence of atomic hydrogen) as the endpoint in an evolution of electronic structures from the monomer.

cond-mat.mtrl-sci↗