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Zhaoshun Gao

Publications and source records attributed to Zhaoshun Gao.

44 records · Page 3Linked to original sources

Superconducting properties of SmO1-xFxFeAs wires with Tc = 52 K prepared by the powder-in-tube method

We demonstrate that Ta sheathed SmO1-xFxFeAs wires were successfully fabricated by the powder-in-tube (PIT) method for the first time. Structural analysis by mean of x-ray diffraction shows that the main phase of SmO1-xFxFeAs was obtained by this synthesis method. The transition temperature of the SmO0.65F0.35FeAs wires was confirmed to be as high as 52 K. Based on magnetization measurements, it is found that a globe current can flow on macroscopic sample dimensions with Jc of ~3.9x10^3 A/cm^2 at 5 K and self field, while a high Jc about 2x10^5 A/cm^2 is observed within the grains, suggesting that a significant improvement in the globle Jc is possible. It should be noted that the Jc exhibits a very weak field dependence behavior. Furthermore, the upper critical fields (Hc2) determined according to the Werthamer-Helfand-Hohenberg formula are (T= 0 K) = 120 T, indicating a very encouraging application of the new superconductors.

cond-mat.supr-con↗

One step synthesis of SmO1-xFxFeAs bulks with Tc = 54.6 K: High upper critical field and critical current density

A safe, simple and easily scaleable one-step sintering method is proposed to fabricate newly discovered superconductors of SmO1-xFxFeAs. Superconducting transition with the onset temperature of 54.6 K and high critical fields Hc2(0) >=200 T were confirmed in SmO1-xFxFeAs with x = 0.3. At 5 K and self field, critical current density Jc estimated from the magnetization hysteresis using the whole sample size and the average particle size reached 8.5x10^3 and 1.2x10^6 A/cm^2, respectively. Moreover, the Jc exhibited a very weak dependence on magnetic field. Microstructural characterizations revealed that the whole sample Jc improvement could be achieved by either perfect texture or optimization of fabrication process in this strongly-layered superconductor. Our results clearly demonstrated that one-step synthesis technique is unique and versatile and hence can be tailored easily for other rare earth derivatives of REFeAsO superconductors.

cond-mat.supr-con↗

Strongly Enhanced Current-Carrying Performance in MgB2 Tape Conductors by Novel C60 Doping

MgB2 is a promising superconductor for important large-scale applications for both high field magnets and cryocooler-cooled magnet operated at temperatures around 20 K. In this work, by utilizing C60 as a viable alternative dopant, we demonstrate a simple and industrially scaleable rout that yields a 10-15-fold improvement in the in-high-field current densities of MgB2 tape conductors. For example, a Jc value higher than 4x10^4 A/cm^2 (4.2 K, 10 T), which exceeds that for NbTi superconductor, can be realized on the C60 doped MgB2 tapes. It is worth noting that this value is even higher than that fabricated using strict high energy ball milling technique under Ar atmosphere. At 20 K, Hirr was about 10 T for C60 doped MgB2 tapes. A large amount of nanometer-sized precipitates and grain boundaries were found in MgB2 matrix. The special physical and chemical characteristic of C60, in addition to its C containing intrinsic essence, is a key point in enhancing the superconducting performance of MgB2 tapes.

cond-mat.supr-con↗

Strong influence of precursor powder on the critical current density of Fe-sheathed MgB2 tapes

The effect of the quality of starting powders on the microstructure and superconducting properties of in-situ processed Fe-sheathed MgB2 tapes has been investigated. Three different types of commercial atomized spherical magnesium powder and two different purities of amorphous boron powder were employed. When using the 10-micrometre magnesium as precursor powders, the Mg reacted with boron more uniformly and quickly, thus the uniformity of the fabricated MgB2 was improved and the grain size of the MgB2 was decreased, hence significant critical current density (Jc) enhancements were achieved for MgB2 tapes. Jc at 4.2 K for MgB2 tapes made from the 10 um Mg and high purity boron powders was at least a factor of ten higher than values measured for MgB2 samples made from all other starting powders. At 20 K, 5 T, the typical Jc values of the tapes were over 1.0x10^4 A/cm^2 and were much better than those of tape samples reported recently.

cond-mat.supr-con↗

Strongly enhanced critical current density in Fe-sheathed MgB2 tapes by stearic acid and stearate doping

Fe-sheathed MgB2 tapes with cheap stearic acid, Mg stearate and Zn stearate doping were prepared through the in situ powder-in-tube method. It is found that Jc, Hirr, and Hc2 were significantly enhanced by doping. Compared to the pure tapes, Jc for all the doped samples was improved by more than an order of magnitude in a high-field regime. At 4.2 K, the transport Jc reached 2.02x10^4 A/cm^2 at 10 T for the Zn stearate doped tapes and 3.72x10^3 A/cm^2 at 14 T for the stearic acid doped samples, respectively, equivalent to that of tapes achieved by nanoscale SiC or carbon doping. The improvement of Jc-H properties in doped samples can be attributed to the increase of Hc2 resulting from the incorporation of C atoms into the MgB2 crystal lattice as well as a high density of flux-pinning centers.

cond-mat.supr-con↗

Improved critical current densities in MgB2 tapes with ZrB2 doping

MgB2/Fe tapes with 2.5-15 at.% ZrB2 additions were prepared through the in situ powder-in-tube method. Compared to the pure tape, a significant improvement in the in-field critical current density Jc was observed, most notably for 10 at.% doping, while the critical temperature decreased slightly. At 4.2 K, the transport Jc for the 10 at.% doped sample increased by more than an order of magnitude than the undoped one in magnetic fields above 9 T. Nanoscale segregates or defects caused by the ZrB2 additions which act as effective flux pinning centers are proposed to be the main reason for the improved Jc field performance.

cond-mat.supr-con↗

Large irreversibility field in nanoscale C-doped MgB2/Fe tape conductors

We investigated the effect of nanoscale-C doping on the critical current density Jc and irreversibility field Birr of Fe-sheathed MgB2 tapes prepared by the in-situ powder-in-tube method. The tapes were heat treated at 600-950C for 1 h. Higher values of Jc and Birr were seen for 5 at.%C-doped MgB2 tapes at higher sintering temperatures, where substantial substitution of boron for carbon occurred. The C-doped samples sintered at 950C showed the highest Birr, for example, at 4.2 K, the Birr reached 22.9 T. In particular, at 20 K, Birr for the C-doped tape achieved 9 T, which is comparable to the upper critical field of the commercial NbTi at 4.2 K. This role of nano-sized C particles can be very beneficial in the fabrication of MgB2 tapes for magnetic resonance imaging applications at 20 K.

cond-mat.supr-con↗

Enhancement of JC-B Properties in MoSi2 doped MgB2 tapes

MoSi2 doped MgB2 tapes with different doping levels were prepared through the in-situ powder-in-tube method using Fe as the sheath material. Effect of MoSi2 doping on the MgB2/Fe tapes was investigated. It is found that the highest JC value was achieved in the 2.5 at.% doped samples, more than a factor of 4 higher compared to the undoped tapes at 4.2 K, 10 T, then further increasing the doping ratio caused a reduction of JC. Moreover, all doped tapes exhibited improved magnetic field dependence of Jc. The enhancement of JC-B properties in MoSi2 doped MgB2 tapes is attributed to good grain linkage and the introduction of effective flux pining centers with the doping.

cond-mat.supr-con↗