arXiv subjects

Zlata Fedorova

Publications and source records attributed to Zlata Fedorova.

11 recordsLinked to original sources

arXiv2026

Scalable Cyclic Olefin Copolymer Encapsulation for High Optical Quality of TMD Monolayers

Monolayer transition metal dichalcogenides (TMDs) combine a direct bandgap, strongly bound excitons, and pronounced second-order optical nonlinearity, which makes them promising materials for ultrathin optoelectronic and nanophotonic devices. However, their optical performance is often degraded by environmental exposure and substrate-induced charge trapping, motivating the development of scalable encapsulation strategies. Here, we investigate spin-coated cyclic olefin copolymer (COC) as a scalable encapsulant for TMDs. Room-temperature and cryogenic optical spectroscopy reveal enhanced photoluminescence and second-harmonic generation, accompanied by excitonic linewidth narrowing and an increased exciton-to-trion ratio. In addition, COC encapsulation induces an excitonic peak splitting and an overall spectral blueshift. First-principles calculations attribute these spectral modifications to local symmetry breaking at the chalcogen interface and macroscopic compressive strain, respectively. These findings establish spin-coated COC as an effective, scalable encapsulation strategy and a potential platform for post-growth excitonic and band-structure engineering.

cond-mat.mtrl-sci↗

arXiv2026

Valleytronics in 2D Materials Roadmap

Valleytronics exploits non-equivalent energy extrema in the electronic band structure of crystalline solids -- the valley degree of freedom -- to encode, manipulate, and read out information. The advent of 2D materials, first graphene and then transition-metal dichalcogenides, made valley control practical through optical, electrical, and magnetic routes. This foundation has enabled remarkable progress in recent years spanning established frontiers, such as valley exciton physics and valley Hall effects, as well as emerging directions including lightwave valleytronics, nanophotonic integration, flat-band valleytronics, and spin-valley qubits. In parallel, there are sustained efforts to scale up valleytronic materials and to predict new valleytronic platforms. This Roadmap brings together perspectives from leading experts to chart the key opportunities and challenges at the forefront of 2D material valleytronics. Each section captures a snapshot of progress in a key research area, identifies critical open challenges, and outlines pathways toward future valleytronics breakthroughs.

cond-mat.mes-hall↗

arXiv2025

Intrinsically chiral exciton polaritons in an atomically-thin semiconductor

Photonic bound states in the continuum (BICs) have emerged as a versatile tool for enhancing light-matter interactions by strongly confining light fields. Chiral BICs are photonic resonances with a high degree of circular polarisation, which hold great promise for spin-selective applications in quantum optics and nanophotonics. Here, we demonstrate a novel application of a chiral BIC for inducing strong coupling between the circularly polarised photons and spin-polarised (valley) excitons (bound electron-hole pairs) in atomically-thin transition metal dichalcogenide crystals (TMDCs). By placing monolayer WS$_2$ onto the BIC-hosting metasurface, we observe the formation of intrinsically chiral, valley-selective exciton polaritons, evidenced by circularly polarised photoluminescence (PL) at two distinct energy levels. The PL intensity and degree of circular polarisation of polaritons exceed those of uncoupled excitons in our structure by an order of magnitude. Our microscopic model shows that this enhancement is due to folding of the Brillouin zone creating a direct emission path for high-momenta polaritonic states far outside the light cone, thereby providing a shortcut to thermalisation (energy relaxation) and suppressing depolarisation. Moreover, while the polarisation of the upper polariton is determined by the valley excitons, the lower polariton behaves like an intrinsic chiral emitter with its polarisation fixed by the BIC. Therefore, the spin alignment of the upper and lower polaritons ($\uparrow\downarrow$ and $\uparrow \uparrow$) can be controlled by $σ^+$ and $σ^-$ polarised optical excitation, respectively. Our work introduces a new type of chiral light-matter quasi-particles in atomically-thin semiconductors and provides an insight into their energy relaxation dynamics.

cond-mat.mes-hall↗

arXiv2025

Valley-dependent emission patterns enabled by plasmonic nanoantennas

Selective control over the emission pattern of valley-polarized excitons in monolayer transition metal dichalcogenides is crucial for developing novel valleytronic, quantum information, and optoelectronic devices. While significant progress has been made in directionally routing photoluminescence from these materials, key challenges remain: notably, how to link routing effects to the degree of valley polarization, and how to distinguish genuine valley-dependent routing from spin-momentum coupling - an optical phenomenon related to electromagnetic scattering but not the light source itself. In this study, we address these challenges by experimentally and numerically establishing a direct relationship between the intrinsic valley polarization of the emitters and the farfield emission pattern, enabling an accurate assessment of valley-selective emission routing. We report valley-selective manipulation of the angular emission pattern of monolayer tungsten diselenide mediated by gold nanobar dimer antennas at cryogenic temperature. Experimentally, we study changes in the system's emission pattern for different circular polarization states of the excitation, demonstrating a valley-selective circular dichroism in photoluminescence of 6%. These experimental findings are supported by a novel numerical approach based on the principle of reciprocity, which allows modeling valley-selective emission in periodic systems. We further show numerically, that these valley-selective directional effects are a symmetry-protected property of the nanoantenna array owing to its extrinsic chirality for oblique emission angles, and can significantly be enhanced when tailoring the distribution of emitters. This renders our nanoantenna-based system a robust platform for valleytronic processing.

physics.optics↗

arXiv2025

Role of Coherence in Polarization Response of Hybrid Monolayer MoS$_2$-Gold Nanoparticle Systems

Monolayers of transition metal dichacogenides show strong second-order nonlinearity and symmetry-driven selection rules from their three-fold lattice symmetry. This process resembles the valley-contrasting selection rules for photoluminescence in these materials. However, the underlying physical mechanisms fundamentally differ since second harmonic generation is a coherent process, whereas photoluminescence is incoherent, leading to distinct interactions with photonic nanoresonators. In this study, we investigate the far-field circular polarization properties of second harmonic generation from MoS$_2$ monolayers resonantly interacting with spherical gold nanoparticles. Our results indicate that the coherence of the second harmonic allows its polarization to be mostly preserved, unlike in an incoherent process, where the polarization is scrambled. These findings provide important insights for future applications in valleytronics and quantum nanooptics, where both coherent and incoherent processes can be probed in such hybrid systems without altering sample geometry or operational wavelength.

physics.optics↗

arXiv2025

Photonics in Flatland: Challenges and Opportunities for Nanophotonics with 2D Semiconductors

Two-dimensional (2D) semiconductors are emerging as a versatile platform for nanophotonics, offering unprecedented tunability in optical properties through exciton resonance engineering, van der Waals heterostructuring, and external field control. These materials enable active optical modulation, single-photon emission, quantum photonics, and valleytronic functionalities, paving the way for next-generation optoelectronic and quantum photonic devices. However, key challenges remain in achieving large-area integration, maintaining excitonic coherence, and optimizing amplitude-phase modulation for efficient light manipulation. Advances in fabrication, strain engineering, and computational modelling will be crucial to overcoming these limitations. This perspective highlights recent progress in 2D semiconductor-based nanophotonics, emphasizing opportunities for scalable integration into photonics.

physics.optics↗

arXiv2024

Influence of resonant plasmonic nanoparticles on optically accessing the valley degree of freedom in 2D semiconductors

The valley degree of freedom is one of the most intriguing properties of atomically thin transition metal dichalcogenides. Together with the possibility to address this degree of freedom by valley-contrasting optical selection rules, it has the potential to enable a completely new class of future electronic and optoelectronic devices. Resonant optical nanostructures emerge as promising tools for interacting with and controlling the valley degree of freedom at the nanoscale. However, a critical understanding gap remains in how nanostructures and their nearfields affect the circular polarization properties of valley-selective emission hindering further developments in this field. In order to address this issue, our study delves into the experimental investigation of a hybrid model system where valley-specific emission from a monolayer of molybdenum disulfide is interacting with a resonant plasmonic nanosphere. Contrary to the simple intuition suggesting that a centrosymmetric nanoresonator preserves the degree of circular polarization in the forward scattered farfield by angular momentum conservation, our cryogenic photoluminescence microscopy reveals that the light emitted from the nanoparticle position is largely unpolarized, i.e. we observe depolarization. We rigorously study the nature of this phenomenon numerically considering the monolayer-nanoparticle interaction at different levels including excitation and emission. In doing so, we find that the farfield degree of polarization strongly reduces in the hybrid system when including excitons emitting from outside of the system's symmetry point, which in combination with depolarisation at the excitation level causes the observed effect. Our results highlight the importance of considering spatially distributed emitters for precise predictions of polarization responses in these hybrid systems.

physics.optics↗

arXiv2022

Observation of the Wannier-Stark ladder in plasmonic waveguide arrays

Evanescently coupled waveguides are a powerful platform to study and visualize the wave dynamics in tight-binding systems. Here, we investigate the propagation of surface plasmon polaritons in arrays of dielectric loaded surface plasmon polariton waveguides with a propagation constant gradient acting as an effective external potential. Using leakage radiation microscopy, we observe in real-space for single site excitation a periodic breathing of the wavepacket and an oscillatory motion in the case of Gaussian excitation of multiple waveguides. The corresponding momentum resolved spectra are composed of sets of equally spaced modes. We interpret these observation as the plasmonic analogues of Bloch oscillations and the Wannier-Stark ladder, respectively.

physics.optics↗

arXiv2022

Real- and Fourier-space observation of the anomalous $π$-mode in Floquet engineered plasmonic waveguide arrays

We present a joint experimental and theoretical study of the driven Su-Schrieffer-Heeger model implemented by arrays of evanescently coupled plasmonic waveguides. Floquet theory predicts that this system hosts for suitable driving frequencies a topologically protected edge state that has no counterpart in static systems, the so-called anomalous Floquet topological $π$-mode. By using real- and Fourier-space leakage radiation microscopy in combination with edge- and bulk excitation, we unequivocally identify the anomalous Floquet topological $π$-mode and study its frequency dependence.

physics.optics↗

arXiv2020

Dissipation engineered directional filter for quantum ratchets

We demonstrate transport rectification in a hermitian Hamiltonian quantum ratchet by a dissipative, dynamic impurity. While the bulk of the ratchet supports transport in both directions, the properly designed loss function of the local impurity acts as a direction-dependent filter for the moving states. We analyse this scheme theoretically by making use of Floquet-S-Matrix theory. In addition, we provide the direct experimental observation of one-way transmittance in periodically modulated plasmonic waveguide arrays containing a local impurity with engineered losses.

cond-mat.mes-hall↗

arXiv2020

Observation of topological transport quantization by dissipation in fast Thouless pumps

Quantized dynamics is essential for natural processes and technological applications alike. The work of Thouless on quantized particle transport in slowly varying potentials (Thouless pumping) has played a key role in understanding that such quantization may be caused not only by discrete eigenvalues of a quantum system, but also by invariants associated with the nontrivial topology of the Hamiltonian parameter space. Since its discovery, quantized Thouless pumping has been believed to be restricted to the limit of slow driving, a fundamental obstacle for experimental applications. Here, we introduce non-Hermitian Floquet engineering as a new concept to overcome this problem. We predict that a topological band structure and associated quantized transport can be restored at driving frequencies as large as the system's band gap. The underlying mechanism is suppression of non-adiabatic transitions by tailored, time-periodic dissipation. We confirm the theoretical predictions by experiments on topological transport quantization in plasmonic waveguide arrays.

quant-ph↗