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arXiv2019

Dynamic nuclear polarisation of liquids at one microtesla using circularly polarised RF with application to millimetre resolution MRI

Magnetic resonance imaging in ultra-low fields is often limited by mediocre signal-to-noise ratio hindering a higher resolution. Overhauser dynamic nuclear polarisation (O-DNP) using nitroxide radicals has been an efficient solution for enhancing the thermal nuclear polarisation. However, the concurrence of positive and negative polarisation enhancements arises in ultra-low fields resulting in a significantly reduced net enhancement, making O-DNP far less attractive. Here, we address this issue by applying circularly polarised RF. O-DNP with circularly polarised RF renders a considerably improved enhancement factor of around 150,000 at 1.2 microtesla. A birdcage coil was adopted into a ultra-low field MRI system to generate the circularly polarised RF field homogeneously over a large volume. We acquired an MR image of a nitroxide radical solution with an average in-plane resolution of 1 mm. De-noising through compressive sensing further improved the image quality.

physics.app-ph↗

arXiv2019

Microstructure and thermal properties of unalloyed tungsten deposited by Wire + Arc Additive Manufacturing

Tungsten is considered as one of the most promising materials for nuclear fusion reactor chamber applications. Wire + Arc Additive Manufacturing has already demonstrated the ability to deposit defect-free large-scale tungsten structures, with considerable deposition rates. In this study, the microstructure of the as-deposited and heat-treated material has been characterised; it featured mainly large elongated grains for both conditions. The heat treatment at 1273 K for 6 hours had a negligible effect on microstructure and on thermal diffusivity. Furthermore, the linear coefficient of thermal expansion was in the range of 4.5x10-6 micron m-1 K-1 to 6.8x10-6 micron m-1 K-1; the density of the deposit was as high as 99.4% of the theoretical tungsten density; the thermal diffusivity and the thermal conductivity were measured and calculated, respectively, and seen to decrease considerably in the temperature range between 300 K to 1300 K, for both testing conditions. These results showed that Wire + Arc Additive Manufacturing can be considered as a suitable technology for the production of tungsten components for the nuclear sector.

physics.app-ph↗

arXiv2018

High Reversibility of Lattice Oxygen Redox in Na-ion and Li-ion Batteries Quantified by Direct Bulk Probes of both Anionic and Cationic Redox Reactions

The reversibility and cyclability of anionic redox in battery electrodes hold the key to its practical employments. Here, through mapping of resonant inelastic X-ray scattering (mRIXS), we have independently quantified the evolving redox states of both cations and anions in Na2/3Mg1/3Mn2/3O2. The bulk-Mn redox emerges from initial discharge and is quantified by inverse-partial fluorescence yield (iPFY) from Mn-L mRIXS. Bulk and surface Mn activities likely lead to the voltage fade. O-K super-partial fluorescence yield (sPFY) analysis of mRIXS shows 79% lattice oxygen-redox reversibility during initial cycle, with 87% capacity sustained after 100 cycles. In Li1.17Ni0.21Co0.08Mn0.54O2, lattice-oxygen redox is 76% initial-cycle reversible but with only 44% capacity retention after 500 cycles. These results unambiguously show the high reversibility of lattice-oxygen redox in both Li-ion and Na-ion systems. The contrast between Na2/3Mg1/3Mn2/3O2 and Li1.17Ni0.21Co0.08Mn0.54O2 systems suggests the importance of distinguishing lattice-oxygen redox from other oxygen activities for clarifying its intrinsic properties.

physics.chem-ph↗

arXiv2019

Zinc Electrode Shape-Change in Secondary Air Batteries: A 2D Modeling Approach

Zinc-air batteries offer large specific energy densities, while relying on abundant and non-toxic materials. In this paper, we present the first multi-dimensional simulations of zinc-air batteries. We refine our existing theory-based model of secondary zinc-air systems. The model comprises thermodynamically consistent multi-species transport in alkaline electrolytes, formation and dissolution of metallic zinc and passivating zinc oxide, as well as multi-phase coexistence in gas diffusion electrodes. For the first time, we simulate zinc shape-change during battery cycling by modeling convection of zinc solids. We validate our model with in-situ tomography of commercial button cells. Two-dimensional volume-averaged simulations of cell voltage and zinc electrode morphology during discharge agree with these measurements. Thus, we can study how electrolyte carbonation limits shelf-life and how zinc shape-change limits cycle-life. The charging current is found to be the major contributor to cycle-life limitations. Finally, we optimize initial anode structure and charge-discharge protocols for improved performance and cycle-ability.

physics.chem-ph↗

arXiv2018

Sound transmission of periodic composite structure lined with porous core: rib-stiffened double panel case

Porous materials are effective for the isolation of sound with medium to high frequencies, while periodic structures are promising for low to medium frequencies. In the present work, we study the sound insulation of a periodically rib-stiffened double-panel with porous lining to reveal the effect of combining the two characters above. The theoretical development of the periodic composite structure, which is based on the space harmonic series and Biot theory, is included. The system equations are subsequently solved numerically by employing a precondition method with a truncation procedure. This theoretical and numerical framework is validated with results from both theoretical and finite element methods. The parameter study indicates that the presence of ribs can lower the overall sound insulation, although a direct transfer path is absent. Despite the unexpected model results, the method proposed here, which combines poroelastic modeling and periodic structures semi-analytically, can be promising in broadband sound modulation.

physics.app-ph↗

arXiv2019

Zirconia UV-curable colloids for additive manufacturing via hybrid inkjet printing-stereolithography

Currently, additive manufacturing of ceramics by stereolithography (SLA) is limited to single materials and by a poor thickness resolution that strongly depends on the ceramic particles-UV light interaction. Combining selective laser curing with inkjet printing represents a novel strategy to overcome these constrains. Nonetheless, this approach requires UV-curable inks that allow hardening of the printed material and sintering to high density. In this work, we report how to design an ink for inkjet printing of yttria stabilized zirconia (YSZ) which can be impressed by addition of UV-curable monomers. We especially show how the formulation of the inks and particularly the UV-monomer concentration impacts the printability and the UV-curing. This leads to prints that are resistant to solvent washing first and densify to 96% dense YSZ layers after sintering.

physics.app-ph↗

arXiv2018

On the thermal rectification factor in steady heat conduction

Thermal rectification in heat conduction problems has been extensively studied in planar slabs. Here we consider the rectification problem in planar, cylindrical and spherical geometries involving two layers one of which has a temperature variable heat conductivity. The rectification factor is analytically calculated. It is shown that a maximum theoretical value of 1.618 is obtained.

physics.app-ph↗

arXiv2018

Maskless laser processing of graphene

Graphene on a SiO$_2$/Si substrate was removed by ultraviolet pulsed laser irradiation. Threshold laser power density to remove graphene depended on the graphene thickness. The mechanism is discussed using kinetic energy of thermal expansion of the substrate surface. Utilizing the thickness dependence, thickness (or layer-number) selective process for graphene is demonstrated. Maskless patterning of graphene using laser irradiation in the air is also demonstrated.

physics.app-ph↗

arXiv2018

Towards Sub-micrometer High Aspect Ratio X-ray Gratings by Atomic Layer Deposition of Iridium

X-ray grating interferometry is an excellent technique for X-ray phase contrast imaging and X-ray wavefront sensing with applications in materials science, biology and medical diagnosis. Among other requirements, the method depends on the availability of highly X-ray absorbing metallic gratings. Here, we report on the fabrication and characterization of high aspect ratio iridium gratings with a period of one micrometer and a depth of 30 micrometer combining deep reactive ion etching of silicon and atomic layer deposition of iridium. The implementation of such structures can greatly enhance the sensitivity of grating-based X-ray phase contrast imaging and thus, expand further its broad range of applications.

physics.app-ph↗

arXiv2018

Overlay Accuracy Limitations of Soft Stamp UV Nanoimprint Lithography and Circumvention Strategies for Device Applications

In this work multilevel pattering capabilities of Substrate Conformal Imprint Lithography (SCIL) have been explored. A mix & match approach combining the high throughput of nanoimprint lithography with the excellent overlay accuracy of electron beam lithography (EBL) has been exploited to fabricate nanoscale devices. An EBL system has also been utilized as a benchmarking tool to measure both stamp distortions and alignment precision of this mix & match approach. By aligning the EBL system to 20 mm x 20 mm and 8 mm x 8 mm cells to compensate pattern distortions of order of $3 μm$ over 6 inch wafer area, overlay accuracy better than $1.2 μm$ has been demonstrated. This result can partially be attributed to the flexible SCIL stamp which compensates deformations caused by the presence of particles which would otherwise significantly reduce the alignment precision.

physics.app-ph↗

arXiv2021

Linear Dependence of Post-irradiation Input Bias Currents on Pre-irradiation Values in Silicon Bipolar Microcircuits

We find in experiments a linear dependence of ionization irradiation-induced degradations on pre-irradiation values of the input bias current in bipolar devices with simple input stages. The dependence is found to generally exist in all studied cases of different device types and different irradiation conditions. A unique behavior of the energy distribution of the interface states ($D_{it}$) under irradiation is suggested as the origin of the observed phenomenon: the generation of interface traps through the depassivation of Si-H bonds located near the pre-irradiation interface traps displays a $D_{it}$ as an enlarge of the initial $D_{it}$ and results in the general linear dependence. A more accurate damage prediction method by using the pre-irradiation values is proposed based on the observed phenomenon.

physics.space-ph↗

arXiv2018

A UV-cured nanofibrous membrane of vinylbenzylated gelatin-poly(ε-caprolactone) dimethacrylate co-network by scalable free surface electrospinning

Electrospun nanofibrous membranes of natural polymers, such as gelatin, are fundamental in the design of regenerative devices. Crosslinking of electrospun fibres from gelatin is required to prevent dissolution in water, to retain the original nanofibre morphology after immersion in water, and to improve the thermal and mechanical properties, although this is still challenging to accomplish in a controlled fashion. In this study, we have investigated the scalable manufacture and structural stability in aqueous environment of a UV-cured nanofibrous membrane fabricated by free surface electrospinning (FSES) of aqueous solutions containing vinylbenzylated gelatin and poly(epsilon-caprolactone) dimethacrylate (PCL-DMA). Vinylbenzylated gelatin was obtained via chemical functionalisation with photopolymerisable 4-vinylbenzyl chloride (4VBC) groups, so that the gelatin and PCL phase in electrospun fibres were integrated in a covalent UV-cured co-network at the molecular scale, rather than being simply physically mixed. UV-cured nanofibrous membranes did not dissolve in water and showed enhanced thermal and mechanical properties, with respect to as-spun samples, indicating the effectiveness of the photo-crosslinking reaction. In addition, UV-cured gelatin/PCL membranes displayed increased structural stability in water with respect to PCL-free samples and were highly tolerated by G292 osteosarcoma cells. These results therefore support the use of PCL DMA as hydrophobic, biodegradable crosslinker and provide new insight on the scalable design of water insoluble, mechanical competent gelatin membranes for healthcare applications.

physics.app-ph↗

arXiv2019

Properties of Al2O3 thin films deposited on 4H-SiC by reactive ion sputtering

In this work, the electrical properties of Al2O3 films deposited by reactive ion sputtering were investigated by means of morphological, chemical and electrical characterizations. This insulating layer suffers of an electron trapping that is mitigated after the rapid thermal annealing (RTA). The RTA improved also the permittivity (up to 6ε0), although the negative fixed charge remains in the order of 1012cm-2. However, the temperature dependent electrical investigation of the MOS capacitors demonstrates that the room temperature Fowler-Nordheim electron barrier height of 2.37 eV lies between the values expected for SiO2/4H-SiC and Al2O3/4H-SiC systems.

physics.app-ph↗

arXiv2017

Flexible transparent high-voltage diodes for energy management in wearable electronics

This work reports flexible fully transparent high-voltage diodes that feature high rectification ratio (Rr 10 8) and high breakdown voltage (Vb 150 V) simultaneously, combined with their applications as building blocks of energy management systems in wearable electronics where triboelectric nanogenerators (TENGs) are used as power source. Both experimental results and technology computer aided design (TCAD) simulations suggest that Rr and Vb can be modulated by the offset length in an opposite tendency. The low reverse leakage current (fA/MICRON) guarantees an ultra-low power consumption in standby mode, which is a core issue in wearable device applications. Besides the unprecedented electrical performance, the diodes exhibit good mechanical robustness with minimal degradation throughout the strain and fatigue tests. By incorporating these high-voltage diodes into half-wave and full-wave rectifier circuits, the high alternating current (AC) output voltage of TENGs is successfully rectified into direct current (DC) voltage and charged into supercapacitors (SCs), indicating their high integration and compatibility with TENGs, and thus their promising applications in various wearable electronic systems.

physics.app-ph↗

arXiv2019

Thermionic-enhanced near-field thermophotovoltaics

Solid-state heat-to-electrical power converters are thermodynamic engines that use fundamental particles, such as electrons or photons, as working fluids. Virtually all commercially available devices are thermoelectric generators, in which electrons flow through a solid driven by a temperature difference. Thermophotovoltaics and thermionics are highly efficient alternatives relying on the direct emission of photons and electrons. However, the low energy flux carried by the emitted particles significantly limits their generated electrical power density potential. Creating nanoscale vacuum gaps between the emitter and the receiver in thermionic and thermophotovoltaic devices enables a significant enhancement of the electron and photon energy fluxes, respectively, which in turn results in an increase of the generated electrical power density. Here we propose a thermionic-enhanced near-field thermophotovoltaic device that exploits the simultaneous emission of photons and electrons through nanoscale vacuum gaps. We present the theoretical analysis of a device in which photons and electrons travel from a hot LaB6-coated tungsten emitter to a closely spaced BaF2-coated InGaAs photovoltaic cell. Photon tunnelling and space charge removal across the nanoscale vacuum gap produce a drastic increase in flux of electrons and photons, and subsequently, of the generated electrical power density. We show that conversion efficiencies and electrical power densities of 30% and 70W/cm2 are achievable at 2000K for a practicable gap distance of 100nm, and thus greatly enhance the performances of stand-alone near-field thermophotovoltaic devices (10% and 10W/cm2). A key practical advantage of this nanoscale energy conversion device is the use of grid-less cell designs, eliminating the issue of series resistance and shadowing losses, which are unavoidable in conventional near-field thermophotovoltaic devices.

physics.app-ph↗

arXiv2018

A complementary compact laser based neutron source

Several experiments of neutron generation using high intensity laser sources, with a power exceeding 10^19W/cm^2 via TNSA (Target Normal Sheath Acceleration) or other similar methods, have been performed in the past years in different laboratories. However, so far there is no one running neutron source based on such a technology. In the framework of the Conceptual Report Design of a new accelerator in the Eupraxia project we are studying the possibility to have a laser-based neutron source, not only by TNSA but also from self-injection schemes. We focus our attention on the applications in cultural heritage studies as well also on the complementary role that such a source can have in the framework of large facilities devoted to radiation production.

physics.acc-ph↗

arXiv2018

Geant4 simulation of the ELIMED transport and dosimetry beam line for high-energy laser-driven ion beam multidisciplinary applications

The ELIMED (MEDical and multidisciplinary application at ELI Beamlines) beam line is being developed at INFN-LNS with the aim of transporting and selecting in energy proton and ion beams accelerated by laser-matter interaction at ELI Beamlines in Prague. It will be a section of the ELIMAIA (ELI Multidisciplinary Applications of laser-Ions Acceleration) beam line, dedicated to applications, including the medical one, of laser-accelerated ion beams [1,2]. A Monte Carlo model has been developed to support the design of the beam line in terms of particle transport efficiency, to optimize the transport parameters at the irradiation point in air and, furthermore, to predict beam parameters in order to deliver dose distributions of clinical relevance. The application has been developed using the Geant4 [3] Monte Carlo toolkit and has been designed in a modular way in order to easily switch on/off geometrical components according to different experimental setups and users requirements, as reported in [4], describing the early-stage code and simulations. The application has been delivered to ELI Beamlines and will be available for future ELIMAIA's users as ready-to-use tool useful during experiment preparation and analysis. The final version of the developed application will be described in detail in this contribution, together with the final results, in terms of energy spectra and transmission efficiency along the in-vacuum beam line, obtained by performing end-to-end simulations.

physics.acc-ph↗

arXiv2018

Novel methods for measuring the optical parameters of the water Cherenkov detector

In this paper, novel methods are presented to measure the optical properties of muon detectors (MDs) in the Large High-Altitude Air Shower Observatory (LHAASO), which can also be used by other experiments. Each MD consists of a cylindrical water Cherenkov detector, with a Tyvek liner containing pure water, and a photomultiplier tube (PMT) mounted on the top. The time distribution of the photons collected by the PMT in the water Cherenkov detector have an approximately exponential distribution, and their decay factor is determined by the photon absorption length in the water, the reflectivity of the inner Tyvek surface, the mean reflecting step length of photons reflected by the inner surface, and the ratio of reflectional Tyvek area to the total inner surface area. By considering the principles of photon propagation in the water Cherenkov detector, we have developed novel methods to measure the water absorption length, the Tyvek reflectivity, and the mean step length of photons. The step length of photons can be determined by measuring the time distribution of the reflected photons hitting the PMT after multiple photons with single wavelength are generated in the tank, with slightly different ratios of the inner Tyvek to the total inner area. The water absorption length and Tyvek reflectivity can be measured simultaneously by the PMT by changing the height of the water, while the step length and Tyvek reflectivity in air can also be measured simultaneously. The proposed novel methods are supported by deduction of formulae and verified by GEANT4 simulations and the prototype experiment.

physics.ins-det↗