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arXiv · 1707.00283

Re-examining Einstein's $B$ coefficient and rate equations with the Rabi model

Najirul Islam·Tanmoy Mondal·Sagar Chakraborty·Shyamal Biswas
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Abstract

Starting from the Rabi Hamiltonian, which is useful in arriving at non-perturbative results within the rotating wave approximation, we have found Einstein's $B$ coefficient to be time-dependent: $B(t)\propto|J_0(ω_γt)|$ for a two-level system (atom or molecule) in thermal radiation field. Here $ω_γ$ is the corresponding Rabi flopping (angular) frequency and $J_0$ is the zeroth order Bessel function of the first kind. The resulting oscillations in the $B$ coefficient---even for very small $ω_γ$---drives the system away from thermodynamic equilibrium at any finite temperature contrary to Einstein's assumption. The time-dependent generalized $B$ coefficient facilitates a path to go beyond Pauli's formalism of non-equilibrium statistical mechanics involving the quantum statistical Boltzmann (master) equation. In this context, we have obtained entropy production of the two-level system by revising Einstein's rate equations, while considering the $A$ coefficient to be the original time-independent one and the $B$ coefficient to be time-dependent.

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Najirul Islam, Tanmoy Mondal, Sagar Chakraborty, Shyamal Biswas. 2019-10-11. Re-examining Einstein's $B$ coefficient and rate equations with the Rabi model. https://doi.org/10.1088/1742-5468%2Fab4fdc

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