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arXiv · 1809.02175

Optical frequency comb photoacoustic spectroscopy

Ibrahim Sadiek·Tommi Mikkonen·Markku Vainio·Juha Toivonen·Aleksandra Foltynowicz
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Abstract

We report the first photoacoustic detection scheme using an optical frequency comb - the optical frequency comb photoacoustic spectroscopy (OFC-PAS). OFC-PAS combines the broad spectral coverage and the high resolution of OFCs with the small sample volume of cantilever-enhanced PA detection. In OFC-PAS, a Fourier transform spectrometer (FTS) is used to modulate the intensity of the exciting comb source at a frequency determined by its scanning speed. One of the FTS outputs is directed to the PA cell and the other is measured simultaneously with a photodiode and used to normalize the PA signal. The cantilever-enhanced PA detector operates in a non-resonant mode, enabling detection of broadband frequency response. The broadband and the high-resolution capabilities of OFC-PAS are demonstrated by measuring the rovibrational spectra of the fundamental C-H stretch band of CH${_4}$, with no instrumental line shape distortions, at total pressures of 1000 mbar, 650 mbar, and 400 mbar. In this first demonstration, a spectral resolution two orders of magnitude higher than previously reported with broadband PAS is obtained, limited by the pressure broadening. A limit of detection of 0.8 ppm of methane in N${_2}$ is accomplished in a single interferogram measurement (200 s measurement time, 1000 MHz resolution, 1000 mbar total pressure) for an exciting power spectral density of 42 {\mu}W/cm${^{-1}}$. A normalized noise equivalent absorption of 8x10${^{-10}}$ W cm${^{-1}}$ Hz${^{-1/2}}$ is obtained, which is only a factor of three higher than the best reported with PAS based on continuous wave lasers. A wide dynamic range of up to four orders of magnitude and a very good linearity (limited by the Beer-Lambert law) over two orders of magnitude are realized. OFC-PAS extends the capability of optical sensors for multispecies trace gas analysis in small sample volume with high resolution and selectivity.

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Ibrahim Sadiek, Tommi Mikkonen, Markku Vainio, Juha Toivonen, Aleksandra Foltynowicz. 2018-09-06. Optical frequency comb photoacoustic spectroscopy. https://doi.org/10.1039/c8cp05666h

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