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arXiv · 1911.12936

All-optical reversible manipulation of exciton and trion emissions in monolayer WS2

Chaoli Yang·Yan Gao·Chengbing Qin·Xilong Liang·Shuangping Han·Guofeng Zhang·Ruiyun Chen·Jianyong Hu·Liantuan Xiao·Suotang Jia
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Abstract

Monolayer transition metal dichalcogenides (TMDs) are direct gap semiconductors emerging promising applications in diverse optoelectronic devices. To improve performance, recent investigations have been systematically focused on the tuning of their optical properties. However, an all-optical approach with the reversible feature is still a challenge. Here we demonstrate the tunability of the photoluminescence (PL) properties of monolayer WS2 via laser irradiation. The modulation of PL intensity, as well as the conversion between neutral exciton and charged trion have been readily and reversibly achieved by using different laser power densities. We attribute the reversible manipulation to the laser-assisted adsorption and desorption of gas molecules, which will deplete or release free electrons from the surface of WS2 and thus modify its PL properties. This all-optical manipulation, with advantages of reversibility, quantitative control, and high spatial resolution, suggests promising applications of TMDs monolayers in optoelectronic and nanophotonic applications, such as optical data storage, micropatterning, and display.

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Chaoli Yang, Yan Gao, Chengbing Qin, Xilong Liang, Shuangping Han, Guofeng Zhang, Ruiyun Chen, Jianyong Hu, Liantuan Xiao, Suotang Jia. 2019-11-29. All-optical reversible manipulation of exciton and trion emissions in monolayer WS2. https://arxiv.org/abs/1911.12936

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