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arXiv · 2003.13927

Conductive Domain Walls in Non-Oxide Ferroelectrics Sn2P2S6

Jianming Deng·Xingan Jiang·Yanyu Liu·Wei Zhao·Yun Li·Ziyan Gao·Peng Lv·Sheng Xu·Tian-Long Xia·Jinchen Wang·Meixia Wu·Zishuo Yao·Xueyun Wang·Jiawang Hong
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Abstract

The conductive domain wall (CDW) is extensively investigated in ferroelectrics, which can be considered as a quasi-two-dimensional reconfigurable conducting channel embedded into an insulating material. Therefore, it is highly important for the application of ferroelectric nanoelectronics. Hitherto, most CDW investigations are restricted in oxides, and limited work has been reported in non-oxides to the contrary. Here, by successfully synthesizing the non-oxide ferroelectric Sn2P2S6 single crystal, we observed and confirmed the domain wall conductivity by using different scanning probe techniques which origins from the nature of inclined domain walls. Moreover, the domains separated by CDW also exhibit distinguishable electrical conductivity due to the interfacial polarization charge with opposite signs. The result provides a novel platform for understanding electrical conductivity behavior of the domains and domain walls in non-oxide ferroelectrics.

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Jianming Deng, Xingan Jiang, Yanyu Liu, Wei Zhao, Yun Li, Ziyan Gao, Peng Lv, Sheng Xu, Tian-Long Xia, Jinchen Wang, Meixia Wu, Zishuo Yao, Xueyun Wang, Jiawang Hong. 2020-03-31. Conductive Domain Walls in Non-Oxide Ferroelectrics Sn2P2S6. https://arxiv.org/abs/2003.13927

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