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arXiv · 2108.06439

Proton distribution visualization in perovskite nickelate devices utilizing nanofocused X-rays

Ivan A. Zaluzhnyy·Peter O. Sprau·Richard Tran·Qi Wang·Hai-Tian Zhang·Zhen Zhang·Tae Joon Park·Nelson Hua·Boyan Stoychev·Mathew J. Cherukara·Martin V. Holt·Evgeny Nazarertski·Xiaojing Huang·Hanfei Yan·Ajith Pattammattel·Yong S. Chu·Shyue Ping Ong·Shriram Ramanathan·Oleg G. Shpyrko·Alex Frano
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Abstract

We use a 30-nm x-ray beam to study the spatially resolved properties of a SmNiO$_3$-based nanodevice that is doped with protons. The x-ray absorption spectra supported by density-functional theory (DFT) simulations show partial reduction of nickel valence in the region with high proton concentration, which leads to the insulating behavior. Concurrently, x-ray diffraction reveals only a small lattice distortion in the doped regions. Together, our results directly show that the knob which proton doping modifies is the electronic valency, and not the crystal lattice. The studies are relevant to on-going efforts to disentangle structural and electronic effects across metal-insulator phase transitions in correlated oxides.

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Ivan A. Zaluzhnyy, Peter O. Sprau, Richard Tran, Qi Wang, Hai-Tian Zhang, Zhen Zhang, Tae Joon Park, Nelson Hua, Boyan Stoychev, Mathew J. Cherukara, Martin V. Holt, Evgeny Nazarertski, Xiaojing Huang, Hanfei Yan, Ajith Pattammattel, Yong S. Chu, Shyue Ping Ong, Shriram Ramanathan, Oleg G. Shpyrko, Alex Frano. 2021-08-14. Proton distribution visualization in perovskite nickelate devices utilizing nanofocused X-rays. https://doi.org/10.1103/physrevmaterials.5.095003

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