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arXiv · 2212.13739

Superconductivity Observed in Tantalum Polyhydride at High Pressure

X. He·C. L. Zhang·Z. W. Li·S. J. Zhang·B. S. Min·J. Zhang·K. Lu·J. F. Zhao·L. C. Shi·Y. Peng·X. C. Wang·S. M. Feng·J. Song·L. H. Wang·V. B. Prakapenka·S. Chariton·H. Z. Liu·C. Q. Jin
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Abstract

We report experimental discovery of tantalum polyhydride superconductor. It was synthesized at high pressure and high temperature conditions using diamond anvil cell combined with in-situ high pressure laser heating techniques. The superconductivity was investigated via resistance measurements at pressures. The highest superconducting transition temperature Tc was found to be ~30 K at 197 GPa in the sample that was synthesized at the same pressure with ~2000 K heating. The transitions are shifted to low temperature upon applying magnetic fields that supports the superconductivity nature. The upper critical field at zero temperature {\mu}0Hc2(0) of the superconducting phase is estimated to be ~20 T that corresponds to GL coherent length ~40 angstroms. Our results suggest that the superconductivity may arise from I-43d phase of TaH3. It is, for the first time to our best knowledge, experimental realization of superconducting hydrides for the VB group of transitional metals.

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X. He, C. L. Zhang, Z. W. Li, S. J. Zhang, B. S. Min, J. Zhang, K. Lu, J. F. Zhao, L. C. Shi, Y. Peng, X. C. Wang, S. M. Feng, J. Song, L. H. Wang, V. B. Prakapenka, S. Chariton, H. Z. Liu, C. Q. Jin. 2022-12-28. Superconductivity Observed in Tantalum Polyhydride at High Pressure. https://doi.org/10.1088/0256-307x%2F40%2F5%2F057404

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