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arXiv · 2308.06437

Modulating the electrochemical intercalation of graphene interfaces with $\alpha$-RuCl$_3$ as a solid-state electron acceptor

Jonathon Nessralla·Daniel T. Larson·Takashi Taniguchi·Kenji Watanabe·Efthimios Kaxiras·D. Kwabena Bediako
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Abstract

Intercalation reactions modify the charge density in van der Waals (vdW) materials through coupled electronic-ionic charge accumulation, and are susceptible to modulation by interlayer hybridization in vdW heterostructures. Here, we demonstrate that charge transfer between graphene and $\alpha$-RuCl$_3$, which dopes the graphene positively, greatly favors the intercalation of lithium ions into graphene-based vdW heterostructures. We systematically tune this effect on Li$^+$ ion intercalation, modulating the intercalation potential, by using varying thicknesses of hexagonal boron nitride (hBN) as spacer layers between graphene and $\alpha$-RuCl$_3$. Confocal Raman spectroscopy and electronic transport measurements are used to monitor electrochemical intercalation and density functional theory computations help quantify charge transfer to both $\alpha$-RuCl$_3$ and graphene upon Li intercalation. This work demonstrates a versatile approach for systematically modulating the electrochemical intercalation behavior of two-dimensional layers akin to electron donating/withdrawing substituent effects used to tune molecular redox potentials.

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Jonathon Nessralla, Daniel T. Larson, Takashi Taniguchi, Kenji Watanabe, Efthimios Kaxiras, D. Kwabena Bediako. 2023-08-12. Modulating the electrochemical intercalation of graphene interfaces with $\alpha$-RuCl$_3$ as a solid-state electron acceptor. https://arxiv.org/abs/2308.06437

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