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arXiv · 2508.18991

Optical charge state manipulation of lead-vacancy centers in diamond

Abstract

Group-IV vacancy centers in diamond exhibit excellent optical and spin coherence properties, making them highly promising and scalable spin qubit candidates. Since only specific charge states are magneto-optically active, control over the charge state is fundamental for quantum applications. Here, we realize the charge state control of lead-vacancy centers (PbV) through multi-color laser irradiation. We achieve tunable population manipulation of the negatively charged state from 0 to 89%, paving the way for spin control of the negatively charged PbV center. Furthermore, through analysis of charge state dynamics, we propose a charge cycle between the neutral and negatively charged states, indicating a possible pathway to the neutral PbV center with a spin-1 system.

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Yiyang Chen, Yoshiyuki Miyamoto, Eiki Ota, Ryotaro Abe, Takashi Taniguchi, Shinobu Onoda, Mutsuko Hatano, Takayuki Iwasaki. 2025-08-26. Optical charge state manipulation of lead-vacancy centers in diamond. https://arxiv.org/abs/2508.18991

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