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arXiv · 2512.09584

Single-crystal growth, structural characterization, and physical properties of a decorated square-kagome antiferromagnet KCu$_7$TeO$_4$(SO$_4$)$_5$Cl

Jingjing Jing·Andreas Eich·Yiqiu Liu·Lunhua He·Aifeng Wang·Yisheng Chai·Young Sun·Yi Cui·Weiqiang Yu·Xinrun Mi·Michael Merz·Mingquan He
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Abstract

The square-kagome lattice, composed of two-dimensional corner-sharing triangles, provides a novel platform for studying frustrated magnetism. However, material realizations of the square-kagome lattice remain scarce. Here, we report the single-crystal growth, structural characterization, magnetic and electric properties of KCu$_7$TeO$_4$(SO$_4$)$_5$Cl, a nabokoite compound featuring a distorted and decorated square-kagome lattice. Weak anomalies near 4 K are observed in both magnetization and specific heat, indicating the onset of a magnetic transition.The formation of a long-range antiferromagnetic state below 4.5 K is further confirmed by $^{35}$Cl nuclear magnetic resonance (NMR) measurements. Magnetic susceptibility data reveal nearly isotropic Curie-Weiss temperatures ($\sim-145$ K) and $g$-factors ($\sim2.4$) for both in-plane and out-of-plane magnetic fields. Moreover, we observe two successive ferroelectric transitions at $T_\mathrm{FE1}\sim30$ K and $T_\mathrm{FE2}\sim27$ K, driven by inversion-symmetry breaking, most likely associated with distortions in the Cu2O$_4$Cl$_1$ pyramids and the adjacent SO$_4$ tetrahedra. These results suggest that a three-dimensional model incorporating interlayer couplings via decorating Cu2 sites is essential for capturing the magnetic and electric behaviors in KCu$_7$TeO$_4$(SO$_4$)$_5$Cl.

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Jingjing Jing, Andreas Eich, Yiqiu Liu, Lunhua He, Aifeng Wang, Yisheng Chai, Young Sun, Yi Cui, Weiqiang Yu, Xinrun Mi, Michael Merz, Mingquan He. 2025-12-10. Single-crystal growth, structural characterization, and physical properties of a decorated square-kagome antiferromagnet KCu$_7$TeO$_4$(SO$_4$)$_5$Cl. https://doi.org/10.1103/zr7m-l3dk

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