arXiv subjects

Young Sun

Publications and source records attributed to Young Sun.

At least 19 recordsLinked to original sources

arXiv2025

Single-crystal growth, structural characterization, and physical properties of a decorated square-kagome antiferromagnet KCu$_7$TeO$_4$(SO$_4$)$_5$Cl

The square-kagome lattice, composed of two-dimensional corner-sharing triangles, provides a novel platform for studying frustrated magnetism. However, material realizations of the square-kagome lattice remain scarce. Here, we report the single-crystal growth, structural characterization, magnetic and electric properties of KCu$_7$TeO$_4$(SO$_4$)$_5$Cl, a nabokoite compound featuring a distorted and decorated square-kagome lattice. Weak anomalies near 4 K are observed in both magnetization and specific heat, indicating the onset of a magnetic transition.The formation of a long-range antiferromagnetic state below 4.5 K is further confirmed by $^{35}$Cl nuclear magnetic resonance (NMR) measurements. Magnetic susceptibility data reveal nearly isotropic Curie-Weiss temperatures ($\sim-145$ K) and $g$-factors ($\sim2.4$) for both in-plane and out-of-plane magnetic fields. Moreover, we observe two successive ferroelectric transitions at $T_\mathrm{FE1}\sim30$ K and $T_\mathrm{FE2}\sim27$ K, driven by inversion-symmetry breaking, most likely associated with distortions in the Cu2O$_4$Cl$_1$ pyramids and the adjacent SO$_4$ tetrahedra. These results suggest that a three-dimensional model incorporating interlayer couplings via decorating Cu2 sites is essential for capturing the magnetic and electric behaviors in KCu$_7$TeO$_4$(SO$_4$)$_5$Cl.

cond-mat.str-el↗

arXiv2025

ac strain based thermodynamic criterion for vortex lattice in type-II superconductors

In type-I superconductors, zero electrical resistivity and perfect diamagnetism define two fundamental criteria for superconducting behavior. In contrast, type-II superconductors exhibit more complex mixed state physics, where magnetic flux penetrates the material above the lower critical field Hc1 in the form of quantized vortices, each carrying a single flux quantum. These vortices form a two dimensional lattice which persists up to another irreversible field (Hirr) and then melts into a dissipative liquid phase. The vortex lattice is fundamental to the magnetic and electrical properties of type II superconductors, ac strain susceptibility-a thermodynamic criterion-for identifying this phase has remained elusive. Here, we report the discovery of a dynamic magnetostrictive effect, wherein the geometry of the superconductor oscillates only under an applied alternating magnetic field due to the disturbance of the vortex lattice. This effect is detected by a thin piezoelectric transducer, which converts the excited geometric deformation into an in-phase ac voltage. Notably, we find a direct and nearly linear relationship between the signal amplitude and the vortex density in lattice across several representative type-II superconductors. In the vortex liquid phase above Hirr, the signal amplitude rapidly decays to zero near the upper critical field (Hc2), accompanied by a pronounced out-of-phase component due to enhanced dissipation. This dynamic magnetostrictive effect not only reveals an unexplored magnetoelastic property of the vortex lattice but also establishes a fundamental criterion for identifying the type-II superconductors.

cond-mat.supr-con↗

arXiv2025

Direct probe of magnetic field effects on phonons by ultrasound propagation in a quasi-two-dimensional honeycomb magnet Na$_2$Co$_2$TeO$_6$

We study the phonon behavior of a Co-based honeycomb frustrated magnet Na$_2$Co$_2$TeO$_6$ under magnetic field applied perpendicular to the honeycomb plane. The temperature and field dependence of the sound velocity and sound attenuation unveil prominent spin-lattice coupling in this material, promoting ultrasound as a sensitive probe for magnetic properties. An out-of-plane ferrimagnetic order is determined below the N\'eel temperature $T_N=27$~K. A comprehensive analysis of our data further supports a triple-Q ground state of Na$_2$Co$_2$TeO$_6$. Furthermore, the ultrasound data were systematically compared to the thermal transport results from literature, to unveil the importance of phononic contribution to the observed transport behaviors.

cond-mat.str-el↗

arXiv2025

Tuning Magnetism of Metal-Organic Framework by Different Types of Pressure

The properties of metal-organic frameworks (MOFs) are expected to be sensitive to external pressures because of their inherently flexible structures. Although pressure-driven structural transitions have been intensively studied, the influence of pressure on magnetism has been less exploited for MOFs. Especially, the efficiency of applied pressure may strongly depend on the pressure-transmitting medium (PTM) which may have a complex interaction with MOFs. Here, we report the distinctive effects of different types of pressure, including isotropic hydrostatic pressure, quasi-hydrostatic pressure, and uniaxial pressure, on the anisotropic magnetism of the perovskite MOF, [CH3NH3][Co(COOH)3]. It is found that the hydrostatic pressure has the minimal effect whereas the uniaxial pressure has the highest efficiency in tuning magnetization and magnetic anisotropy of the MOF. First-principles calculations reveal that the applied low pressures (less than 11 kbar) do not induce notable lattice distortion in the framework or the superexchange path. Instead, the modulation of hydrogen bonds is identified as a critical factor for pressure tuning of magnetization and anisotropy. These findings underscore the potential applications of directional pressure in precisely controlling the magnetic and electronic properties of MOFs.

cond-mat.mtrl-sci↗

arXiv2025

Semiconducting behaviors at epitaxial Ca0.5TaO3 interfaces

Emergent phenomena take place in symmetry-breaking systems, notably the recently discovered two-dimensional electron gas and its tunable superconductivities near the KTaO3 interfaces. Here, we synthesized perovskite Ca0.5TaO3 films along both [001] and [111] orientations. Different from the KTaO3 system, Ca0.5TaO3 films show semiconducting behaviors when capped with LaAlO3 films in both [001] and [111] orientations. By growing films at higher temperatures, more oxygen vacancies can be introduced, and the carrier density can be tuned from ~ 1014 cm-2 to ~ 1016 cm-2. Another difference is that the superconducting transition temperature Tc in KTaO3 (111) increases linearly along with its carrier density, while the Ca0.5TaO3 (111) remains semiconducting when carrier density ranges from ~ 1014 cm-2 to ~ 1016 cm-2. Based on the density function theory calculation, Ca0.5TaO3 and KTaO3 show similar electronic band structures. According to the energy-dispersive X-ray spectroscopy, we found heavy Sr diffusion from the substrate to the Ca0.5TaO3 layer, which may destroy the interfacial conductivity. Our work demonstrates that besides the oxygen vacancies, electronic transport is sensitive to the atomic intermixing near the interface in tantulates.

cond-mat.mtrl-sci↗

arXiv2025

Electromagnon signatures of a metastable multiferroic state

Magnetoelectric multiferroic materials, particularly type-II multiferroics where ferroelectric polarizations arise from magnetic order, offer significant potential for the simultaneous control of magnetic and electric properties. However, it remains an open question as to how the multiferroic ground states are stabilized on the free-energy landscape in the presence of intricate competition between the magnetoelectric coupling and thermal fluctuations. In this work, by using terahertz time-domain spectroscopy in combination with an applied magnetic field, photoexcitation, and single-shot detection, we reveal the spectroscopic signatures of a magnetic-field-induced metastable multiferroic state in a hexaferrite. This state remains robust until thermal influences cause the sample to revert to the original paraelectric state. Our findings shed light on the emergence of metastable multiferroicity and its interplay with thermal dynamics.

cond-mat.str-el↗

arXiv2024

Ferromagnetism and structural phase transition in monoclinic FeGe film

Binary compound FeGe hosts multiple structures, from cubic and hexagonal to monoclinic. Compared to the well-known skyrmion lattice in the cubic phase and the antiferromagnetic charge-density wave in the hexagonal phase, the monoclinic FeGe is less explored. Here, we synthesized the monoclinic FeGe films on Al2O3 (001) and studied their structural, magnetic, and transport properties. X-ray diffraction and transmission electron microscopy characterizations indicate that the FeGe films are epitaxial to the substrate. Unlike the antiferromagnetic bulk, the monoclinic FeGe films are ferromagnetic with Curie-temperature as high as ~ 800 K, contributing to the anomalous Hall effect in the transport measurements. Similar to the hexagonal FeGe, we captured a structural phase transition in the monoclinic FeGe films at ~ 100 K in real and reciprocal spaces by transmission electron microscope. Our work enriches the phase diagram of the FeGe family and suggests that FeGe offers an ideal platform for studying multiphase transitions and related device applications.

cond-mat.mtrl-sci↗

arXiv2024

Pressure tuning of hydrogen bond ordering in the metal-organic framework [(CH3)2NH2]Mn(HCOO)3

The influence of pressure on the hydrogen bond ordering in the perovskite metal-organic framework [(CH3)2NH2]Mn(HCOO)3 has been investigated by dielectric, pyroelectric adn magnetic measurements in a piston-cylinder cell. Under ambient pressure the ordering of hydrogen bonds takes place at TC = 188 K and induces a first-order ferroelectric phase transition. With increasing pressure to p = 3.92 kbar, the order-disorder transition shifts to a lower temperature and retains the first-order ferroelectric nature. However, under higher pressures, the ordering process of hydrogen bonds is split into two transitions: a broad antiferroelectric transition at high temperature and a first-order ferroelectric transition at low temperature. With increasing pressure, the antiferroelectric phase is enhanced whereas the ferroelectric phase is greatly suppressed, which implies that compression of the perovskite framework favors antiparallel arrangement of the hydrogen bonds. The canted anti-ferromagnetic transition was almost unchanged when pressure up to 10.85 kbar. Our study demonstrated that the perovskite metal-organic frameworks are more sensitive to external pressure than conventional perovskite oxides so that their electric properties can be easily tuned by pressure.

cond-mat.mtrl-sci↗

arXiv2024

Resonant Quantum Magnetodielectric Effect in Multiferroic Metal-Organic Framework [CH3NH3]Co(HCOO)3

We report the observation of both resonant quantum tunneling of magnetization (RQTM) and resonant quantum magnetodielectric (RQMD) effect in the perovskite multiferroic metal-organic framework [CH3NH3]Co(HCOO)3. An intrinsic magnetic phase separation emerges at low temperatures due to hydrogen-bond-modified long range super-exchange interaction, leading to the coexistence of canted antiferromagnetic order and single-ion magnet. Subsequently, a stair-shaped magnetic hysteresis loop along the [101] direction characterizing the RQTM appears below the magnetic blocking temperature. More interestingly, the magnetic field dependence of dielectric permittivity exhibits pronounced negative peaks at the critical fields corresponding to the RQTM, a phenomenon termed the RQMD effect which enables electrical detection of the RQTM. These intriguing properties make the multiferroic metal-organic framework a promising candidate for solid-state quantum computing.

cond-mat.mtrl-sci↗

arXiv2024

Pressure tunable magnetic skyrmion phase in Co8Zn8Mn4 single crystals

In a magnetic skyrmion phase, magnetic moments form vortex-like topological textures which are of both fundamental and industrial interests. In $\beta$-Mn-type Co-Zn-Mn alloys, chrial magnetic skyrmions emerge above room temperature, providing a unique system for studying the skrymion physics and exploring spintronics applications. However, the magnetic skyrmion phase is typically confined in a narrow and limited temperature ($T$) and magnetic field ($H$) range. Here, we demonstrate that hydrostatic pressure can expand the skyrmion phase in the $T-H$ phase diagram of single-crystalline Co$_8$Zn$_8$Mn$_4$. At ambient pressure, signatures of skyrmions are seen within $T\sim302-308$ K and $H\sim50-100$ Oe. Applying a moderate pressure of 6 kbar extends this range to $T\sim300-310$ K and $H\sim50-150$ Oe. However, further escalation of pressure to 10 kbar results in a slight contraction of the skyrmion phase. These findings underscore the sensitivity of the skyrmion phase in Co$_8$Zn$_8$Mn$_4$ to external pressures, and hint at the potential of strain engineering, particularly in $\beta$-Mn-type Co-Zn-Mn thin films, as a promising avenue to customize the skyrmion phase.

cond-mat.mtrl-sci↗

arXiv2023

Non-volatile memory based on PZT/FeGa thin film memtranstor

The PZT/FeGa thin film memtranstor was prepared and the modulation of the magnetoelectric coefficient by external magnetic and electric fields was studied. The magnetoelectric coefficient of the PZT/FeGa memtranstor can be reversed by flipping the direction of magnetization of FeGa or ferroelectric polarization of PZT. Notably, the sign of the magnetoelectric coefficient can be switched repeatedly by reversing ferroelectric polarization of PZT when the external magnetic field remains constant. Moreover, the binary switching behavior can still be maintained under zero DC bias magnetic field. When the polarization direction remains stable, the magnetoelectric coefficient also does not change. This means that the magnetoelectric coefficient of PZT/FeGa is non-volatile. Furthermore, the retention and endurance characteristics of the PZT/FeGa thin film memtranstor have been investigated. These findings demonstrate the potential of the PZT/FeGa thin film memtranstor for non-volatile memory applications.

physics.app-ph↗

arXiv2023

Comprehensive investigation of Quantum Oscillations in Semimetal Using an ac Composite Magnetoelectric Technique with Ultrahigh Sensitivity

Quantum oscillation (QO), a physical phenomenon that reflects the characteristics of the Fermi surface and transport fermions, has been extensively observed in metals and semimetals through various approaches, like magnetostriction, magnetization, resistivity, and thermoelectric power. However, only some allowed oscillation frequencies can be revealed by each individual method, particularly in semimetals with intricate Fermi pockets and associated magnetic breakdown phenomena. In this paper, we present the application of an ac composite magnetoelectric (ME) technique to measure the QOs of a topological nodal-line semimetal, ZrSiS, which possesses six fundamental QO frequencies. By employing the ME technique with a maximum magnetic field of 13 T and a minimum temperature of 2 K, we are able to capture all the fundamental frequencies and most of the permissible magnetic breakdown frequencies. In comparison, some of the frequencies were missing in the aforementioned four methods under identical measurement conditions. Remarkably, a series of magnetic breakdown frequencies around 8000 T were revealed even in a magnetic field as low as 7.5 T. These findings highlight the ME technique as an ultrahigh-sensitive tool for studying Dirac Fermions and other topological semimetals with complex Fermi surfaces.

cond-mat.str-el↗

arXiv2022

Tuning of Quantum Paraelectricity of M-type Hexaferrite BaFe12O19 by External Parameters

M-type hexaferrite BaFe12O19 was recently reported to be a new type of quantum paraelectrics with triangular lattice by showing a low temperature dielectric plateau due to quantum fluctuation. It has also been proposed to have a possible quantum-dipole liquid ground state. To suppress its quantum fluctuations and reach a possible quantum critical point, we have tuned its quantum paraelectricity in three ways: (i) 57Fe isotope replacement; (ii) in-plane compressive strain; and (iii) hydrostatic pressure. It is found that 95% 57Fe replacement and the in-plane strain are more effective to drive its ground state closer to a critical region by inducing a peak feature in the temperature dependence of dielectric constant. In contrast, the application of hydrostatic pressure pushed the system away from the quantum critical point by gradually suppressing the plateau feature in dielectric constant. Our combined efforts reveal the potential of the M-type hexaferrites for studying the quantum critical behaviors.

cond-mat.str-el↗

arXiv2022

Multi-state data storage in a two-dimensional stripy antiferromagnet implemented by magnetoelectric effect

A promising approach to the next generation of low-power, functional, and energy-efficient electronics relies on novel materials with coupled magnetic and electric degrees of freedom. In particular, stripy antiferromagnets often exhibit broken crystal and magnetic symmetries, which may bring about the magnetoelectric (ME) effect and enable the manipulation of intriguing properties and functionalities by electrical means. The demand for expanding the boundaries of data storage and processing technologies has led to the development of spintronics toward two-dimensional (2D) platforms. This work reports the ME effect in the 2D stripy antiferromagnetic insulator CrOCl down to a single layer. By measuring the tunneling resistance of CrOCl on the parameter space of temperature, magnetic field, and applied voltage, we verified the ME coupling down to the 2D limit and unraveled its mechanism. Utilizing the multi-stable states and ME coupling at magnetic phase transitions, we realize multi-state data storage in the tunneling devices. Our work not only advances the fundamental understanding of spin-charge coupling but also demonstrates the great potential of 2D antiferromagnetic materials to deliver devices and circuits beyond the traditional binary operations.

cond-mat.mtrl-sci↗

arXiv2022

Observation of enhanced spin-spin correlations at triple point in 2D ferromagnetic Cr2X2Te6 (X=Si, Ge)

The domain dynamics and spin-spin correlation of 2D ferromagnets Cr2X2Te6 (X=Si, Ge) are investigated by a composite magnetoelectric method. The magnetic field-temperature phase diagrams for both in-plane and out-of-plane magnetic fields disclose a triple point around TC and 1 kOe, where ferromagnetic, paramagnetic, and spin-polarized phases coexist. The magnetoelectric signal shows peak features at the phase boundaries and reaches the maximum at the triple point, suggesting significant enhancement of spin-spin correlations at this point. A comparison between two systems reveals that the spin-spin correlations in Cr2Si2Te6 are stronger than that in Cr2Ge2Te6.

cond-mat.mtrl-sci↗

arXiv2022

Evidence for distortion-induced local electric polarization in $\alpha$-RuCl$_3$

The spin-orbit assisted Mott insulator $\alpha$-RuCl$_3$ is a prime candidate for material realization of the Kitaev quantum spin liquid. While little attention has been paid to charge degrees of freedom, charge effects, such as electric polarization, may arise in this system. Here, we report distortion-induced local electric polarization in $\alpha$-RuCl$_3$ as evidenced by single-crystal X-ray diffraction, second harmonic generation (SHG) and dielectric measurements. The SHG signal appears at room temperature and develops substantially in the Kitaev paramagnetic state when short-range spin correlations come into play. Despite sizable pyroelectric currents in the Kitaev paramagnetic state, the absence of hysteresis in electric field-dependent polariza-tion (P-E) points to the short-range nature of electric polarization. This localized electric polarization is likely the result of distortion-induced charge dimerization, achieved through virtual hopping-induced charge redistribution. In addition, the electric polarization is boosted by short-range spin correlations via spin-phonon coupling in the Kitaev paramagnetic state. Our results emphasize the importance of charge degrees of freedom in $\alpha$-RuCl$_3$, which establish a novel platform to investi-gate charge effects in Kitaev materials.

cond-mat.str-el↗

arXiv2022

Comparison of skyrmion phases between poly and single-crystal MnSi by composite magnetoelectric method

We have explored the skyrmion phases and phase diagram of poly and single-crystal MnSi by the measurements of the magnetoelectric coefficient alfaE and ac magnetic susceptibility of the MnSi/PMN-PT composite. We found that the regular skyrmion lattice phase in single crystal sample has been averaged in the MnSi polycrystal due to random grain orientations which results in an extended skyrmion lattice-conical mixture phase down to 25 K. The magnitude of the out-of-phase component in alfaE of the polycrystal, not single crystal, decreases gradually with decreasing frequency. With the changing of the driven ac field, it reveals a depinning threshold behavior in both samples. The depinning field is stronger in the polycrystal than that in single crystal and maybe responsible for the diminishing of dissipative behavior at lower frequency due to grain boundaries and defects. The composite magnetoelectric method provides a unique approach to probe topological phase dynamics.

cond-mat.mtrl-sci↗

arXiv2021

Comprehensive characterizing of vortex phases in type-II superconductor YBa2Cu3O7-x by a magnetoelectric technique

The vortex phases in type-II superconductors are very important since they determine many magnetic and electric properties of the parent compound. However, a universal tool to characterize the vortex phases is still lacking. We demonstrate in a type-II superconductors YBa2Cu3O7-x polycrystal sample that its vortex phases and phase boundaries can be comprehensively studied by a magnetoelectric technique. In this method, a thin piezoelectric material 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3(PMN-PT) is mechanically bonded with YBa2Cu3O7-x to form a laminate structure and act as a strain gauge. The phase diagram of the YBa2Cu3O7-x polycrystalline was explored by this method. Surprisingly, it can accurately estimate the Hc1, irreversible line, Hc2 and distinguish among vortex glass, vortex liquid, non-vortex states. Moreover, it can probe the dynamic response under different frequencies and observe the threshold phenomena of vortex liquid phase. It can even account for the density of vortices in the vortex solid phase. Our technique is readily extended to investigate the vortex phases in other type-II superconductors.

cond-mat.supr-con↗