Electrical manipulation of oxygen stoichiometry in multiterminal YBa$_2$Cu$_3$O$_{7-\delta}$ junctions

Abstract

Local manipulation of oxygen stoichiometry offers a route to control the electronic properties of complex oxides, yet the selective modification of individual current-carrying branches through oxygen redistribution remains unexplored in multiterminal high-temperature superconducting junctions. In a YBa$_2$Cu$_3$O$_{7-\delta}$ Y-shaped three-terminal device, we demonstrate the possibility to electrically control oxygen vacancy migration on a hand-picked terminal while largely preserving the other two. Oxygen-depleted propagating fronts are directly visualized by the resulting change in optical reflectivity and they are linked to the evolution of the electrical response. The process is highly directional and determined by the polarity of the applied current, allowing for the creation of either a converging or a diverging propagating front from the central node of the Y-shaped device. The associated changes in resistance exhibit relaxation on a timescale of minutes, driven by the vacancy concentration gradient. Effects of oxygen migration are also mapped by Kelvin Probe Force Microscopy and Scanning Laser Microscopy, which probe work-function changes and spatially resolved variations in the superconducting transition, respectively. Notably, the Tc contrast revealed by the latter provides a quantitative handle on the underlying oxygen content, enabling direct visualization of oxygen redistribution. Finite-element modeling and nanoprobe X-ray diffraction qualitatively reproduce the observed vacancy redistribution. These results establish a post-fabrication route to locally tune properties of superconducting multiterminal devices such as nanocryotrons, yTron, and tunable weak links.