Kinetic equation for liquids with a multistep potential of interaction. II: Calculation of transport coefficients

M. V. Tokarchuk; I. P. Omelyan; A. E. Kobryn

doi:10.1103/physreve.62.8021

Home/Archive/arXiv

arXiv · cond-mat/9910070

Kinetic equation for liquids with a multistep potential of interaction. II: Calculation of transport coefficients

M. V. Tokarchuk·I. P. Omelyan·A. E. Kobryn

View original source ↗Read source document ↗Export metadata ↓

Abstract

We consider a new kinetic equation for systems with a multistep potential of interaction proposed by us recently in Physica A 234 (1996) 89. This potential consists of the hard sphere part and a system of attractive and repulsive walls. Such a model is a generalization of many previous semi-phenomenological kinetic theories of dense gases and liquids. In this article a normal solution to the new kinetic equation has been obtained, integral conservation laws in the first order on gradients of hydrodynamic parameters have been derived as well. The expressions for transport coefficients are calculated for the case of stationary process. We also consider limiting cases for this kinetic equation. For specific parameters of model interaction potential in shape of the multistep function, the obtained results rearrange to those of previous kinetic theories by means of the standard Chapman-Enskog method. In view of this, new theory can be considered as a generalized one which in some specific cases arrives at the results of previous ones and in such a way displays the connection of these theories between themselves. At the end of this article we present results of numerical computation of transport coefficients for Argon along curve of saturation and their comparison with experimental data available and MD simulations.

Explore related subjects

cond-mat.stat-mech cond-mat.soft

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

M. V. Tokarchuk, I. P. Omelyan, A. E. Kobryn. 1999-10-06. Kinetic equation for liquids with a multistep potential of interaction. II: Calculation of transport coefficients. https://doi.org/10.1103/physreve.62.8021

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Universal sampling of spin systems across quenched disorder

Statistical physics extracts macroscopic laws by averaging over the many microscopic degrees of freedom of a system. Disordered systems demand a second and far harder average, one over the quenched randomness itself. The classic analytical routes, the replica and cavity methods, become uncontrolled outside mean-field or tree-like limits, and conventional numerical algorithms like parallel tempering require expensive, independent equilibration for every disorder realization. In this work, we introduce a universal neural variational framework that amortizes inference across the disorder ensemble, eliminating both the need for per-instance Markov chain equilibration and the cost of retraining instance-specific variational ansatzes. Built on an encoder-decoder Transformer architecture, after training once, it produces an explicit approximation to the Boltzmann distribution given previously unseen disorder realizations without further optimization. We validate this framework on 2D Edwards-Anderson models, and apply it to the random-bond Ising model, successfully capturing the Binder cumulant crossings near the Nishimori multicritical point. These results shift the object of variational inference from the single instance to the disorder ensemble, opening a route to frustrated many-body systems where instance-by-instance computation is prohibitive.

cond-mat.stat-mech↗

arXiv2026

Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation

Open chemical reaction networks exhibit stochastic concentration dynamics at finite system sizes, whereas their macroscopic limit is governed by deterministic rate equations that can display chaos. In this Letter, we show theoretically that a rate of information loss constructed from two-time mutual information recovers the Kolmogorov-Sinai entropy in the deterministic limit. We verify this result through numerical simulations of a Markov jump process for a three-species system involving seven reactions.

cond-mat.stat-mech↗

arXiv2026

Orientational order on non-orientable domains

We study the statistical properties of passive and active many-body systems with orientational degrees of freedom on non-orientable domains. By rephrasing topological constraints as non-local symmetry relations on an orientable double-cover, we show that non-orientability eliminates global rotational soft modes without acting like an external field. In a passive XY model, this results in topological caging, where orientational fluctuations that exhibit conventional diffusive behavior on a torus saturate on a Klein bottle to a finite value that we compute exactly in the thermodynamic limit. In models of active self-propelled particles with orientational degrees of freedom, topological caging persists despite continuously changing interaction neighborhoods. In an active Ising spin model, non-orientability enforces the coexistence of ordered anti-parallel domains with vanishing global polar order, a state that is absent on orientable domains.

cond-mat.stat-mech↗