arXiv subjects

Kentaro Kuga

Publications and source records attributed to Kentaro Kuga.

At least 19 recordsLinked to original sources

arXiv2026

Semiclassical thermoelectric transport in disordered Dirac electron system Ag2Te

We investigated the thermoelectric effects of the Dirac electron system Ag2Te under magnetic field. Our anal-ysis based on the Boltzmann semiclassical model associated the disorder with the unconventional magnetic field responses such as linear magnetoresistance, linear Nernst effect, step-like Nernst effect, and sign change in Nernst effect. The analysis also revealed the impurity band near the Fermi energy. We simultaneously clari-fied the serious impact of the thermal Hall effect on the measurement of the Nernst effect, and we proposed the definitive solution. Our careful measurement and analysis will be the standard for the thermoelectric study under magnetic field.

cond-mat.mtrl-sci↗

arXiv2025

Evidence for energy-dependent scattering dominating thermoelectricity in heavy fermion systems

In the field of thermoelectric materials and devices, improving energy conversion efficiency remains a long-standing challenge. As a promising approach to address this issue, utilizing energy-dependent electron-scattering beyond the ordinary constant relaxation time approximation (CRTA) has been proposed. However, direct experimental evidence for an energy-dependent scattering reflected in the Seebeck coefficient is still lacking. Here we demonstrate using angle-resolved photoemission spectroscopy that the relaxation time of heavy fermion quasiparticles is highly dependent on the energy near the Fermi level. The observed energy dependence of the relaxation time is due to the coherent Kondo scattering, describing the sign of the Seebeck coefficient reasonably well, which cannot be deduced from CRTA. Our findings provide not only deeper insight into the understanding of thermoelectricity in correlated materials, but also future perspectives on possible orbital-selective engineering of thermoelectric materials.

cond-mat.str-el↗

arXiv2024

Coupling of magnetism and transport properties to the lattice degrees of freedom in NdBaCo$_2$O$_{5+{\delta}}$ ($\delta \sim 0.65$)

We have studied the origin of zero volume expansion below the Curie temperature (Tc), variable range hopping (VRH) behaviour using structural, magnetic, transport and thermal studies on the oxygen deficient double perovskite NdBaCo$_2$O$_{5+{\delta}}$ ($\delta \sim 0.65$). The valence state of Co ions and the possible properties exhibited by such compound were studied using electronic structure calculations for $\delta = 0.75$. Careful investigation of structure shows that the compound stabilizes in tetragonal structure (P4/mmm) having $2a_p \times 2a_p \times 2a_p$ (222) superstructure, where $a_p$ is the cubic perovskite lattice parameter. The compound exhibits a minimum in resistivity, ferromagnetic and ferrimagnetic transitions around 375 K, 120 K ($T_c$) and 60 K, respectively with signature of Griffiths phase above $T_c$. Our detailed structural analysis suggests signature of the onset of the above magnetic transitions at temperatures well above its stabilisation at long range level thereby leading to VRH behaviour. The observed zero thermal expansion in volume below Tc appears to be due to competing magnetic interactions within and between the magnetic sublattices. Our electronic structure calculations show (a) the importance of electron-electron correlation in Nd $4f$ and Co $3d$ states (b) Co ions stabilize in intermediate spin (IS) state, having oxidation state less than +3 (c) half metallicity. Our results show the possibility of coupling between magnetism and ferroelectricity. We believe that our results especially on the valence state of the Co ion, zero thermal expansion in volume, short range magnetic orderings and the connection between different degrees of freedom will be helpful in clearing the ambiguities existing in literature on the nature of magnetism and thereby aiding in designing new functionalities.

cond-mat.str-el↗

arXiv2022

Lattice effects on the physical properties of half doped perovskite ruthenates

We investigate the unusual phase transitions in SrRuO$_{3}$ and Sr$_{0.5}$Ca$_{0.5}$Ru$_{1-x}$Cr$_{x}$O$_{3}$ (x=0,0.05 and 0.1) employing x-ray diffraction, resistivity, magnetic studies and x-ray photoemission spectroscopy. Our results show the compounds undergo crossover from $itinerant$ ferromagnetism to $localised$ ferromagnetism. The combined studies suggests Ru and Cr to be in 4+ valence state. A Griffith phase and an enhancement in Curie temperature (Tc) from 38 K to 107 K is observed with Cr doping. A shift in the chemical potential towards the valence band is observed with Cr doping. In the metallic samples, interestingly, a direct link between the resistivity and orthorhombic strain is observed. Detailed studies in this direction will be helpful to understand the nature of interactions and hence manoeuvre its properties. In the non metallic samples, the resistivity is mainly governed by disorder and electron-electron correlation effects. The value of the resistivity for the 5% Cr doped sample suggests semi metallic behaviour. Understanding its nature in detail using electron spectroscopic techniques could unravel the possibility of its utility in high mobility transistors at room temperature and its combined property with ferromagnetism will be helpful in making spintronic devices.

cond-mat.str-el↗

arXiv2022

Observation of a Critical Charge Mode in a Strange Metal

Quantum electronic matter has long been understood in terms of two limiting behaviors of electrons: one of delocalized metallic states, and the other of localized magnetic states. Understanding the strange metallic behavior which develops at the brink of localization demands new probes of the underlying electronic charge dynamics. Using a state-of-the-art technique, synchrotron-radiation-based Mossbauer spectroscopy, we have studied the longitudinal charge fluctuations of the strange metal phase of beta-YbAlB4 as a function of temperature and pressure. We find that the usual single absorption peak in the Fermi-liquid regime splits into two peaks upon entering the critical regime. This spectrum is naturally interpreted as a single nuclear transition, modulated by nearby electronic valence fluctuations whose long time-scales are further enhanced, due to the formation of charged polarons. Our results represent a direct observation of critical charge fluctuations as a new signature of strange metals.

cond-mat.str-el↗

arXiv2021

Tuning the structural, electronic and magneto-transport properties of spin-orbit Mott insulator Sr2IrO4

We investigate the tunability of the structural, electronic and magneto transport properties of polycrystalline Sr2IrO4 sample. The extent of bifurcation of the magnetisation curves during the field cooled and zero field cooled cycles establishes that the magnetic anisotropy in the as-prepared sample is more as compared to the vacuum annealed one. Based on the behaviours of the structural parameters and the magnetic studies, our results show that the canted AFM structure is stabilised in a larger temperature range in the case of the annealed sample as compared to the as prepared one. At low temperatures, for both the samples, a phase, possibly of glassy nature competes with the canted AFM phase. The temperature extent to which both these phases co-exist for the as-prepared and the annealed one is around 115K an 70K, respectively. The transport studies reveal that for both the samples, in the high temperature region of study, the conduction mechanism is governed by the Arrhenius model. In the intermediate temperature range, variable range hopping(VRH) and Arrhenius models govern the transport in the as-prepared and the annealed one, respectively. At low temperatures, the conduction mechanism occurs through Efros-Shklovskii-VRH and VRH mechanisms for the as-prepared and the annealed samples, respectively. The magneto resistance measurements indicate higher negative magneto resistance in the annealed sample at all temperatures. The field dependence of magneto resistance at 10K suggests a co-existing glassy magnetic phase along with the canted antiferromagnetic structure in the as prepared sample and a suppression of this glassy magnetic phase in the annealed sample. The combined analyses of all the results highlight the role of disorder for the magnetic and trasnport properties of this compound.

cond-mat.str-el↗

arXiv2021

Synergetic enhancement of power factor and suppression of lattice thermal conductivity via electronic structure modification and nanostructuring on Ni and B co-doped p-type Si-Ge alloy

For simultaneously achieving the high-power factor and low lattice thermal conductivity of Si-Ge based thermoelectric materials, we employed, in this study, constructively modifying the electronic structure near the chemical potential and nano-structuring by low temperature and high-pressure sintering on nano-crystalline powders. Nickel was doped to create the impurity states near the edge of the valence band for enhancing the power factor with boron for tuning the carrier concentration. The nanostructured samples with the nominal composition of Si0.65-xGe0.32Ni0.03Bx (x = 0.01, 0.02, 0.03, and 0.04) were synthesized by the mechanical alloying followed low-temperature and high-pressure sintering process. A large magnitude of Seebeck coefficient reaching 321 {\mu}VK-1 together with a small electrical resistivity of 4.49 m{\Omega}cm, leads to a large power factor of 2.3 Wm-1K-2 at 1000 K. With successfully reduced thermal conductivity down to 1.47 Wm-1K-1, a large value of ZT ~1.56 was obtained for Si0.65-xGe0.32Ni0.03B0.03 at 1000 K

cond-mat.mtrl-sci↗

arXiv2020

Strong in-plane anisotropy in the electronic structure of fixed-valence $\beta$-LuAlB$_4$

The origin of intrinsic quantum criticality in the heavy-fermion superconductor $\beta$-YbAlB$_4$ has been attributed to strong Yb valence fluctuations and its peculiar crystal structure. Here, we assess these contributions individually by studying the isostructural but fixed-valence compound $\beta$-LuAlB$_4$. Quantum oscillation measurements and DFT calculations reveal a Fermi surface markedly different from that of $\beta$-YbAlB$_4$, consistent with a `large' Fermi surface there. We also find an unexpected in-plane anisotropy of the electronic structure, in contrast to the isotropic Kondo hybridization in $\beta$-YbAlB$_4$.

cond-mat.str-el↗

arXiv2019

Characterization of in-gap states in epitaxial CoFe2O4(111) layers grown on Al2O3(111)/Si(111) by resonant inelastic x-ray scattering

We have studied in-gap states in epitaxial CoFe2O4(111), which potentially acts as a perfect spin filter, grown on a Al2O3(111)/Si(111) structure by using ellipsometry, Fe L2,3-edge x-ray absorption spectroscopy (XAS), and Fe L2,3-edge resonant inelastic x-ray scattering (RIXS), and revealed the relation between the in-gap states and chemical defects due to the Fe2+ cations at the octahedral sites (Fe2+ (Oh) cations). The ellipsometry measurements showed the indirect band gap of 1.24 eV for the CoFe2O4 layer and the Fe L2,3-edge XAS confirmed the characteristic photon energy for the preferential excitation of the Fe2+ (Oh) cations. In the Fe L3-edge RIXS spectra, a band-gap excitation and an excitation whose energy is smaller than the band-gap energy (Eg = 1.24 eV) of CoF2O4, which we refer to as "below-band-gap excitation (BBGE)" hereafter, were observed. The intensity of the BBGE was strengthened at the preferential excitation energy of the Fe2+ (Oh) cations. In addition, the intensity of the BBGE was significantly increased when the thickness of the CoFe2O4 layer was decreased from 11 to 1.4 nm, which coincides with the increase in the site occupancy of the Fe2+ (Oh) cations with decreasing the thickness. These results indicate that the BBGE comes from the in-gap states of the Fe2+ (Oh) cations whose density increases near the heterointerface on the bottom Al2O3 layer. We have demonstrated that RIXS measurements and analyses in combination with ellipsometry and XAS are effective to provide an insight into in-gap states in thin-film oxide heterostructures.

cond-mat.mtrl-sci↗

arXiv2019

Quantum critical behaviour and Lifshitz transition in intermediate valence $\alpha$-YbAlB$_4$

Intermetallic compounds containing $f$-electron elements have been prototypical materials for investigating strong electron correlations and quantum criticality (QC). Their heavy fermion ground state evoked by the magnetic $f$-electrons is susceptible to the onset of quantum phases, such as magnetism or superconductivity, due to the enhanced effective mass ($m^{*}$) and a corresponding decrease of the Fermi temperature. However, the presence of $f$-electron valence fluctuations to a non-magnetic state is regarded an anathema to QC, as it usually generates a paramagnetic Fermi-liquid state with quasiparticles of moderate $m^{*}$. Such systems are typically isotropic, with a characteristic energy scale $T_0$ of the order of hundreds of kelvins that require large magnetic fields or pressures to promote a valence or magnetic instability. Here we show that the intermediate valence compound $\alpha$-YbAlB$_4$ surprisingly exhibits both quantum critical behaviour and a Lifshitz transition under low magnetic field, which is attributed to the anisotropy of the hybridization between the conduction and localized $f$-electrons. These findings suggest a new route to bypass the large valence energy scale in developing the QC.

cond-mat.str-el↗

arXiv2018

Effect of Anisotropic Hybridization in YbAlB$_4$ Probed by Linear Dichroism in Core-Level Hard X-ray Photoemission Spectroscopy

We have probed the crystalline electric-field ground states of pure $|J = 7/2, J_z = \pm 5/2\rangle$ as well as the anisotropic $c$-$f$ hybridization in both valence fluctuating systems $\alpha$- and $\beta$-YbAlB$_4$ by linear polarization dependence of angle-resolved core level photoemission spectroscopy. Interestingly, the small but distinct difference between \abyb was found in the polar angle dependence of linear dichroism, indicating the difference in the anisotropy of $c$-$f$ hybridization which may be essential to a heavy Fermi liquid state in $\alpha$-YbAlB$_4$ and a quantum critical state in $\beta$-YbAlB$_4$.

cond-mat.str-el↗

arXiv2018

High temperature antiferromagnetism in Yb based heavy fermion systems proximate to a Kondo insulator

Given the parallelism between the physical properties of Ce and Yb based magnets and heavy fermions due to the electron-hole symmetry, it has been rather odd that the transition temperature of the Yb based compounds is normally very small, as low as $\sim$ 1 K or even lower, whereas Ce counterparts may often have the transition temperature well exceeding 10 K. Here, we report our experimental discovery of the transition temperature reaching 20 K for the first time in a Yb based compound at ambient pressure. The Mn substitution at the Al site in an intermediate valence state of $\alpha$-YbAlB$_{4}$ not only induces antiferromagnetic transition at a record high temperature of 20 K but also transforms the heavy fermion liquid state in $\alpha$-YbAlB$_{4}$ into a highly resistive metallic state proximate to a Kondo insulator.

cond-mat.str-el↗

arXiv2017

Frustrated magnetism in the Heisenberg pyrochlore antiferromagnets $A$Yb$_2$$X$$_4$ ($A$ = Cd, Mg, $X$ = S, Se)

Our polycrystalline sample study on the Yb-based chalcogenide spinels $A$Yb$_2$$X_4$ ($A =$ Cd, Mg, $X =$ S, Se) has revealed frustrated magnetism due to the antiferromagnetically coupled Heisenberg spin on the pyrochlore lattice. Our crystal electric field analysis indicates the Yb ground state has nearly Heisenberg spins with a strong quantum character of the ground doublet. All the materials exhibit an antiferromagnetic order at 1.4-1.8 K, much lower temperature than the antiferromagnetic exchange coupling scale of $\sim 10$ K. The magnetic specific heat $C_{\rm M}$ shows a $T^{3}$ dependence, indicating the gapless feature in the Yb-based chalcogenide spinels. The magnetic entropy change much smaller than $R$ ln 2 below the Néel temperature and the small local magnetic field estimated from the $μ$SR measurements strongly suggest the significantly reduced size of the ordered moment in comparison with the bare moment size 1.33 $μ_{\rm B}$/Yb supporting strong fluctuations in the commensurate and incommensurate ordered states in CdYb$_2$S$_4$ and MgYb$_2$S$_4$, respectively.

cond-mat.str-el↗

arXiv2016

Pressure-induced magnetic transition exceeding 30 K in the Yb-based heavy fermion superconductor $β$-YbAlB$_4$

Measurements of the electric resistivity $ρ(T)$ under pressure up to 8 GPa were performed on high-quality single-crystals of the Yb-based heavy fermion system $β$-YbAlB$_4$ in the temperature range $2<T<$ 300 K. In the resistivity data, we observed pressure-induced magnetic ordering above the critical pressure $P_{\rm c} \sim$ 2 GPa. Clear difference in the phase diagram under pressure using two types of pressure mediums indicates that the transition temperature may be further enhanced under application of uniaxial pressure. With pressure, this phase transition temperature $T_{\rm M}$ is enhanced reaching 32 K at 8 GPa, which is the highest transition temperature so far recorded for the Yb-based heavy fermion compounds. The power-law exponent $α$ in $ρ=ρ_0+ AT^α$ below $T_{\rm M}$ gradually changes from 3/2 to 5/2 with increasing pressure from 2 to 8 GPa. In contrast, the resistivity exhibits a $T$-linear behavior in the temperature range 2 $\le T \le$ 20 K and is insensitive to pressure below $P_{\rm c}$. In this pressure regime, the magnetization is also nearly independent of pressure and shows no anomaly above 2 K. Our results indicate that a quantum critical point for $β$-YbAlB$_4$ is also located near $P_{\rm c}$ in addition to the strange metal region near the ambient pressure.

cond-mat.str-el↗

arXiv2015

Strange metal without magnetic criticality

A fundamental challenge to our current understanding of metals is the frequent observation of qualitative departures from Fermi liquid behavior. The standard view attributes such non-Fermi liquid phenomena to the scattering of electrons off quantum critical fluctuations of an underlying order parameter. While the possibility of non-Fermi liquid behavior isolated from the border of magnetism has long been speculated, no experimental confirmation has been made. Here we report on the observation of a strange metal region in the absence of a magnetic instability in an ultrapure single crystal. In particular, we show that the heavy fermion superconductor $β$-YbAlB$_4$ forms a possible phase with strange metallic behavior across an extensive pressure regime, distinctly separated from a high-pressure magnetic quantum phase transition by a Fermi liquid phase.

cond-mat.str-el↗

arXiv2015

High Pressure Measurements of the Resistivity of $β$-YbAlB$_4$

The electric resistivity $ρ(T)$ under hydrostatic pressure up to 8 GPa was measured above 2 K using a high-quality single crystal of the Yb-based heavy fermion system $β$-YbAlB$_4$. We found pressure-induced magnetic ordering above the critical pressure $P_{\rm c} \approx $ 2.4 GPa. This phase transition temperature $T_M$ is enhanced with pressure and reaches 30 K at a pressure of 8 GPa, which is the highest transition temperature for the Yb-based heavy fermion compounds. In contrast, the resistivity is insensitive to pressure below $P_c$ and exhibits the $T$-linear behavior in the temperature range between 2 and 20 K. Our results indicate that quantum criticality for $β$-YbAlB$_4$ is also located near $P_{\rm c}$ in addition to the ambient pressure.

cond-mat.str-el↗

arXiv2014

Anisotropic transverse magnetoresistivity in alpha-YbAlB4

We measured the transverse magnetoresistivity of the mixed valence compound $α$-YbAlB$_4$. Two configurations were used where current was applied along [110] direction for both and magnetic field was applied along [-110] and $c$-axis. We found the transverse magnetoresistivity is highly anisotropic. In the weak field below 1 T, it is consistent with stronger $c$-$f$ hybridization in the $ab$ plane which was suggested from the previous zero field resistivity measurements. At the higher field above 3 T, we observed a negative transverse magnetoresistivity for the field applied along the $c$-axis. The temperature dependences of the resistivity measured at several different fields suggest the suppression of the heavy fermion behavior at the characteristic field of $\sim 5.5$ T.

cond-mat.str-el↗

arXiv2012

Magnetic order induced by Fe substitution of Al site in the heavy fermion systems alpha-YbAlB4 and beta-YbAlB4

beta-YbAlB4 is a heavy fermion superconductor that exhibits a quantum criticality without tuning at zero field and under ambient pressure. We have succeeded in substituting Fe for Al in beta-YbAlB4 as well as the polymorphous compound alpha-YbAlB4, which in contrast has a heavy Fermi liquid ground state. Full structure determination by single crystal X-ray diffraction confirmed no change in crystal structure for both alpha- and beta-YbAlB4, in addition to volume contraction with Fe substitution. Our measurements of the magnetization and specific heat indicate that both alpha-YbAl0.93Fe0.07B4 and beta-YbAl0.94Fe0.06B4 exhibit a magnetic order, most likely of a canted antiferromagnetic type, at $7\sim 9$ K. The increase in the entropy as well as the decrease in the antiferromagnetic Weiss temperature with the Fe substitution in both systems indicates that the chemical pressure due to the Fe substitution suppresses the Kondo temperature and induces the magnetism.

cond-mat.str-el↗