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Qing Zhao

Publications and source records attributed to Qing Zhao.

At least 109 records · Page 6Linked to original sources

Non-parametric Probabilistic Time Series Forecasting via Innovations Representation

Probabilistic time series forecasting predicts the conditional probability distributions of the time series at a future time given past realizations. Such techniques are critical in risk-based decision-making and planning under uncertainties. Existing approaches are primarily based on parametric or semi-parametric time-series models that are restrictive, difficult to validate, and challenging to adapt to varying conditions. This paper proposes a nonparametric method based on the classic notion of {\em innovations} pioneered by Norbert Wiener and Gopinath Kallianpur that causally transforms a nonparametric random process to an independent and identical uniformly distributed {\em innovations process}. We present a machine-learning architecture and a learning algorithm that circumvent two limitations of the original Wiener-Kallianpur innovations representation: (i) the need for known probability distributions of the time series and (ii) the existence of a causal decoder that reproduces the original time series from the innovations representation. We develop a deep-learning approach and a Monte Carlo sampling technique to obtain a generative model for the predicted conditional probability distribution of the time series based on a weak notion of Wiener-Kallianpur innovations representation. The efficacy of the proposed probabilistic forecasting technique is demonstrated on a variety of electricity price datasets, showing marked improvement over leading benchmarks of probabilistic forecasting techniques.

cs.LG↗

Multi-qubit State Tomography with Few Pauli Measurements

In quantum information transformation and quantum computation, the most critical issues are security and accuracy. These features, therefore, stimulate research on quantum state characterization. A characterization tool, Quantum state tomography, reconstructs the density matrix of an unknown quantum state. Theoretically, reconstructing an unknown state using this method can be arbitrarily accurate. However, this is less practical owing to the huge burden of measurements and data processing for large numbers of qubits. Even comprising an efficient estimator and a precise algorithm, an optimal tomographic framework can also be overburdened owing to the exponential growth of the measurements. Moreover, the consequential postprocessing of huge amounts of data challenges the capacity of computers. Thus, it is crucial to build an efficient framework that requires fewer measurements but yields an expected accuracy. To this end, we built a tomography schema by which only a few Pauli measurements enable an accurate tomographic reconstruction. Subsequently, this schema was verified as efficient and accurate through numerical simulations on the tomography of multi-qubit quantum states. Furthermore, this schema was proven to be robust through numerical simulations on a noisy superconducting qubit system. Therefore, the tomography schema paves an alternatively effective way to reconstruct the density matrix of a quantum state owing to its efficiency and accuracy, which are essential for quantum state tomography.

quant-ph↗

Research on the transition dynamics and linear (nonlinear) optical properties of mCherry

In this study, we explore the electron transition mechanism and optical properties of the popular red fluorescent protein mCherry. By examining the charge transfer spectrum and combining it with the mCherry hole-electron distribution, we identify that the charge transfer between the phenolate and imidazolinone loops significantly contributes to the absorption spectrum. Quantitative analysis of charge transfer shows that, overall, the electrons are transferred to the C16 atom in the middle of phenolate and the imidazolinone loops during absorption. We speculate that C16 may also absorb protons to enable the photoconversion of mCherry in the excited state, similar to the blinking mechanism of IrisFP. In addition, we further investigated the optical properties of mcherry in the external field by polarizability (hyperpolarizability), showing the anisotropy of the polarization, the first hyperpolarization and the second hyperpolarization by unit spherical representation. Our results suggest that significant polarization and second hyperpolarizability occur when the field direction and electron transfer direction are aligned. We also analyzed the polarizability and first hyperpolarizabilities for different external fields. The polarizability mutated when the external field satisfies the S_0,min-> S_1 transition. Finally, the study of the first hyperpolarizability shows that adjusting the appropriate field can lead to a linear photoelectric effect or second harmonic generation of mCherry. These studies have certain reference values for various red fluorescent protein correlation simulations and experiments because of the similarity of the red fluorescent protein.

physics.chem-ph↗

Collaborative Learning in Kernel-based Bandits for Distributed Users

We study collaborative learning among distributed clients facilitated by a central server. Each client is interested in maximizing a personalized objective function that is a weighted sum of its local objective and a global objective. Each client has direct access to random bandit feedback on its local objective, but only has a partial view of the global objective and relies on information exchange with other clients for collaborative learning. We adopt the kernel-based bandit framework where the objective functions belong to a reproducing kernel Hilbert space. We propose an algorithm based on surrogate Gaussian process (GP) models and establish its order-optimal regret performance (up to polylogarithmic factors). We also show that the sparse approximations of the GP models can be employed to reduce the communication overhead across clients.

stat.ML↗

An mCherry biolaser based on microbubble cavity with ultra-low threshold

Biolasers show considerable potential in the biomedical field. Fluorescent protein (FP) is a type of biomaterial with good luminescence efficiency that can be used as the luminescent gain medium in biolasers. Due to the higher cell/tissue permeability, lower cell phototoxicity, and relatively less background fluorescence than other fluorescent proteins, the red fluorescent protein is more suitable in biological applications. MCherry is the most extensively used high-quality red fluorescent protein because of its short maturation time and stable luminescence properties. In this study, using mCherry and microbubble cavity, we realize a highly stable mCherry fluorescent protein laser. The laser resonator achieves a quality factor of 10^8, which is the highest Q factor among the currently available FP lasers. Moreover, this laser exhibits low threshold of 286 fJ, which can effectively protect the luminescent material from being damaged by pump light. Such a threshold is the lowest in the FP lasers as per our knowledge. The prepared laser shows excellent stability in a wide pH range with good photobleaching resistance and can be stored at 4 degree for nearly a month. Also, the laser can serve as a high-sensitivity molecular concentration detector with mCherry as biomarker, owing to its lasing threshold behavior.

physics.optics↗

Client Selection for Generalization in Accelerated Federated Learning: A Multi-Armed Bandit Approach

Federated learning (FL) is an emerging machine learning (ML) paradigm used to train models across multiple nodes (i.e., clients) holding local data sets, without explicitly exchanging the data. It has attracted a growing interest in recent years due to its advantages in terms of privacy considerations, and communication resources. In FL, selected clients train their local models and send a function of the models to the server, which consumes a random processing and transmission time. The server updates the global model and broadcasts it back to the clients. The client selection problem in FL is to schedule a subset of the clients for training and transmission at each given time so as to optimize the learning performance. In this paper, we present a novel multi-armed bandit (MAB)-based approach for client selection to minimize the training latency without harming the ability of the model to generalize, that is, to provide reliable predictions for new observations. We develop a novel algorithm to achieve this goal, dubbed Bandit Scheduling for FL (BSFL). We analyze BSFL theoretically, and show that it achieves a logarithmic regret, defined as the loss of BSFL as compared to a genie that has complete knowledge about the latency means of all clients. Furthermore, simulation results using synthetic and real datasets demonstrate that BSFL is superior to existing methods.

cs.LG↗

Single-pixel imaging of a translational object

Image-free tracking methods based on single-pixel detectors (SPDs) can track a moving object at a very high frame rate, but they rarely can achieve simultaneous imaging of such an object. In this study, we propose a method for simultaneously obtaining the relative displacements and images of a translational object. Four binary Fourier patterns and two differential Hadamard patterns are used to modulate one frame of the object and then modulated light signals are obtained by SPD. The relative displacements and image of the moving object can be gradually obtained along with the detection. The proposed method does not require any prior knowledge of the object and its motion. The method has been verified by simulations and experiments, achieving a frame rate of 3332 Hz to acquire relative displacements of a translational object at a spatial resolution of $128 \times 128$ pixels using a 20000-Hz digital micro-mirror device. This proposed method can broaden the application of image-free tracking methods and obtain spatial information about moving objects.

physics.optics↗

Towards simultaneous coherent radiation in the visible and microwave bands with doped molecular crystals

Coherent sources exploiting the stimulated emission of non-equilibrium quantum systems, i.e. gain media, have proven indispensable for advancing fundamental research and engineering. The operating electromagnetic bands of such coherent sources have been continuously enriched for increasing demands.Nevertheless, for a single bench top coherent source, simultaneous generation of radiation in multiple bands, especially when the bands are widely separated, present formidable challenges with a single gain medium. Here, we propose a mechanism of simultaneously realizing the stimulated emission of radiation in the visible and microwave bands, i.e. lasing and masing actions, at ambient conditions by utilizing photoexcited singlet and triplet states of the pentacene molecules that are doped in p-terphenyl. The possibility is validated by the observed amplified spontaneous emission (ASE) at 645 nm with a narrow linewidth around 1 nm from the pentacene-doped p-terphenyl crystal used for masing at 1.45 GHz and consolidated by a 20 fold lower threshold of ASE compared to the reported masing threshold. The overall threshold of the pentacene-based multiband coherent source can be optimized by appropriate alignment of the pump-light polarization with the pentacene's transition dipole moment. Our work not only shows a great promise on immediate realization of multiband coherent sources but also establishes an intriguing solid-state platform for fundamental research of quantum optics in multiple frequency domains.

physics.optics↗

In vitro evaluation of a novel Mg-Sn-Ge ternary alloy for orthopedic applications

Magnesium (Mg) and its alloys have attracted considerable attention owing to their excellent biodegradable properties and biocompatibility. Novel Mg-Sn-Ge ternary Mg alloys were developed as potential biodegradable materials for orthopedic applications because of their alloying elements naturally present in humans. The feasibility of these alloys was investigated in terms of mechanical properties, degradation, cytocompatibility, and hemocompatibility. The hardness and elastic modulus of Mg-2Sn-xGe alloys were improved significantly by increasing the Ge content. Among all the alloys, the Mg-2Sn-3Ge alloy displays outstanding biodegradable properties, as evidenced by the electrochemical tests and hydrogen evolution. The degradation products detected on the corroded alloy surfaces weaken at higher Ge levels. The in vitro cytotoxicity assay and hemolysis test showed that the Mg-2Sn-xGe alloys exhibit favorable biocompatibility and hemocompatibility, except for the Mg-2Sn-2Ge alloy.

physics.med-ph↗

Distributed Linear Bandits under Communication Constraints

We consider distributed linear bandits where $M$ agents learn collaboratively to minimize the overall cumulative regret incurred by all agents. Information exchange is facilitated by a central server, and both the uplink and downlink communications are carried over channels with fixed capacity, which limits the amount of information that can be transmitted in each use of the channels. We investigate the regret-communication trade-off by (i) establishing information-theoretic lower bounds on the required communications (in terms of bits) for achieving a sublinear regret order; (ii) developing an efficient algorithm that achieves the minimum sublinear regret order offered by centralized learning using the minimum order of communications dictated by the information-theoretic lower bounds. For sparse linear bandits, we show a variant of the proposed algorithm offers better regret-communication trade-off by leveraging the sparsity of the problem.

cs.LG↗

Novelty Detection in Time Series via Weak Innovations Representation: A Deep Learning Approach

We consider novelty detection in time series with unknown and nonparametric probability structures. A deep learning approach is proposed to causally extract an innovations sequence consisting of novelty samples statistically independent of all past samples of the time series. A novelty detection algorithm is developed for the online detection of novel changes in the probability structure in the innovations sequence. A minimax optimality under a Bayes risk measure is established for the proposed novelty detection method, and its robustness and efficacy are demonstrated in experiments using real and synthetic datasets.

cs.LG↗

Wafer-level substrate-free low-stress silicon nitride platform for THz metadevices and monolithically integrated narrowband metamaterial absorbers

The implementation of terahertz (THz) wafer-level metadevices is critical to advance the science for applications including (I) integrated focal plane array which can image for biology and (II) integrated narrowband absorbers for high spectral resolution THz spectroscopy. Substantial progress has been made in the development of THz metamaterials; however, a wafer-level low-stress THz metadevices platform remains a challenge. This paper experimentally demonstrates a substrate-free THz metadevices platform adopting engineered Si-rich and low-stress silicon nitride (SiNx) thin films, achieving an extensive THz transparency up to f = 2.5 THz. A new analytical model is first reported from the Lorentz model that can accurately predict spectral responses of metal insulator metal (MIM) metamaterial absorbers. The model is experimentally validated in the THz range and exploited for the first demonstration of a THz absorber, which exhibits performance approaching the predicted results. Our results show that the wafer-level SiNx platform will accelerate the development of large-scale, sophisticated substrate-free THz metadevices. The Lorentz model and its quadratic model will be a very practical method for designing THz metadevices.

physics.optics↗

The Sabatier principle for Battery Anodes: Chemical Kinetics and Reversible Electrodeposition at Heterointerfaces

How surface chemistry influences reactions occurring thereupon has been a long-standing question of broad scientific and technological interest for centuries. Recently, it has re-emerged as a critical question in a subdiscipline of chemistry - electrochemistry at heterointerphases, where the answers have implications for both how, and in what forms, humanity stores the rising quantities of renewable electric power generated from solar and wind installations world-wide. Here we consider the relation between the surface chemistry at such interphases and the reversibility of electrochemical transformations at a rechargeable battery electrode. Conventional wisdom holds that stronger chemical interaction between the metal deposits and electrode promotes reversibility. We report instead that a moderate strength of chemical interaction between the deposit and the substrate, neither too weak nor too strong, enables highest reversibility and stability of the plating/stripping redox processes at a battery anode. Analogous to the empirical Sabatier principle for chemical heterogeneous catalysis, our finding arises from the confluence of competing processes - one driven by electrochemistry and the other by chemical alloying. Based on experimental evaluation of metal plating/stripping systems in battery anodes of contemporary interest, we show that such knowledge provides a powerful tool for designing key materials in highly reversible electrochemical energy storage technologies based on earth-abundant, low-cost metals.

physics.chem-ph↗

Unresolved excess accumulation of myelin-derived cholesterol contributes to scar formation after spinal cord injury

Background: Spinal cord injury triggers complex pathological cascades, resulting in destructive tissue damage and incomplete tissue repair. Scar formation is generally considered as a barrier for regeneration in central nervous system (CNS), while the intrinsic mechanism of scar-forming after spinal cord injury has not been completed deciphered. Methods: We assessed cholesterol hemostasis in spinal cord lesions and injured peripheral nerves using confocal reflection microscopy and real-time PCR analyses. The involvement of the proteins, which were predicted to promote cholesterol efflux in spinal cord lesions, were assessed with Liver X receptor (LXR) agonist and Apolipoprotein E (APOE) deficiency. The role of reverse cholesterol transport (RCT) in cholesterol clearance was examined in APOE KO mice injured sciatic nerves and myelin-overloaded macrophages in vitro. Finally, we determined the consequence of excess cholesterol accumulation in CNS by transplantation of myelin into neonatal spinal cord lesions. Results: We found that excess cholesterol accumulates in phagocytes and is inefficiently removed in spinal cord lesions in young-adult mice. Interestingly, we observed that excessive cholesterol also accumulates in injured peripheral nerves, but is subsequently removed by RCT. Meanwhile, preventing RCT led to macrophage accumulation and fibrosis in injured peripheral nerves. Furthermore, the neonatal mouse spinal cord lesions are devoid of myelin-derived lipids, and able to heal without excess cholesterol accumulation. We found that transplantation of myelin into neonatal lesions disrupts healing with excessive cholesterol accumulation, persistent macrophage activation and fibrosis, indicating myelin-derived cholesterol plays a critical role in impaired wound healing.

q-bio.TO↗

Finite particle-number description of symmetric nuclear matter with spin excitations of high-momentum pairs induced by tensor force

We study the symmetric nuclear matter using bare nucleon-nucleon ($NN$) interactions with finite particle-number approach within finite cubic boxes. Due to the $NN$ correlations originating from bare $NN$ interaction, two nucleons can be excited to the high-momentum region, leading to the increase of the kinetic energy in nuclear matter. We further consider the spin excitations in the nucleon pairs, where the spin of the two nucleons are changed, and this excitation is important for the tensor correlation. The unitary correlation operator method (UCOM) is used to treat the short-range correlation. The tail correction coming from the neighbouring boxes is also included. We demonstrate the contributions of various excitations of nucleon pairs as well as the tail correction to the total energy at the normal density. We also discuss the effects of UCOM and correlated nucleon pairs on the density dependence of the total energy. We calculate the equations of state of symmetric nuclear matter using two kinds of the Argonne potentials and the results agree with those from other many-body theories. The density dependences of the Hamiltonian components are also shown.

nucl-th↗

A detail-enhanced sampling strategy in Hadamard single-pixel imaging

Hadamard single-pixel imaging (HSI) is an appealing imaging technique due to its features of low hardware complexity and industrial cost. To improve imaging efficiency, many studies have focused on sorting Hadamard patterns to obtain reliable reconstructed images with very few samples. In this study, we present an efficient HSI imaging method that employs an exponential probability function to sample Hadamard spectra along a direction with better energy concentration for obtaining Hadamard patterns. We also propose an XY order to further optimize the pattern-selection method with extremely fast Hadamard order generation while retaining the original performance. We used the compressed sensing algorithm for image reconstruction. The simulation and experimental results show that these pattern-selection method reliably reconstructs objects and preserves the edge and details of images.

eess.IV↗

Far-field diffraction computational imaging based on parameter-robust illumination and direct phase optimization

Coherent diffraction imaging (CDI) is a promising imaging technique revealing most of the information from diffraction measurements. An ideal CDI should reconstruct complex-valued object from a single-shot far-field diffraction without any priori information about the target. To realize the ideal CDI, we propose a class of parameter-robust illumination pattern. A direct phase optimizing algorithm is also raised here to improve the performance of phase retrieval in strong noise. Experimental result demonstrates the efficiency of our scheme in practical noisy measurement for complex-valued target.

physics.optics↗

The study of the alpha formation probability in 10Be and 12Be within the microscopic cluster model

The alpha clustering in the 10Be and 12Be has been studied within the framework of the real-time evolution method (REM). By using the effective interaction tuned to reproduce the charge radii and the threshold energies, we have evaluated the alpha reduced width amplitude (RWA) and spectroscopic factor (S-factor) for the ground and excited states. With several improvements made in this work, comparing with our previous calculations, larger rate of clustering results are obtained for the 10Be and 12Be with correct asymptotic at large distance.

nucl-th↗