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Takahide Yamaguchi

Publications and source records attributed to Takahide Yamaguchi.

35 records · Page 2Linked to original sources
arXiv2012

Electrodeposition as a new route to synthesize superconducting FeSe

We have successfully synthesized FeSe films by the electrochemical deposition in the electrolyte containing FeCl_{2}\cdot4H_{2}O, SeO_{2} and Na_{2}SO_{4}. The composition ratio of Fe and Se was controlled by the synthesis voltage and pH value. The FeSe film with the composition ratio of Fe : Se = 1 : 1 is fabricated at a voltage of -0.9 V and pH 2.1 in our electrochemical deposition. This sample has a highly crystalline tetragonal FeSe structure and exhibits a superconducting transition at 8.1 K, comparable to FeSe synthesized by other methods.

cond-mat.supr-con↗
arXiv2012

One-step synthesis of KxFe2-ySe2 single crystals for high critical current density

We have established a simple process that allows for the one-step synthesis of KxFe2-ySe2 single crystals, which exhibit high critical current density Jc. The post annealing and quenching technique has improved the homogeneity of as-grown crystals, resulting in full shielding of the external magnetic field. The quenched crystals show a superconducting transition at Tconset = 32.9 K and Tczero = 32.1 K. The upper critical fields μ_{0}Hc2(0) for H//ab and H//c are estimated to be ~206 and ~50 T, respectively. The critical current densities Jc for H//ab and H//c reach as high as 1.0\times10^{5} and 3.4\times10^{4} A/cm2 at 5 K. Furthermore, Jc exhibits a high field performance and a significantly weak temperature dependence up to 5 T, suggesting strong pinning. These results demonstrate that KxFe2-ySe2 would be a promising candidate material for practical applications.

cond-mat.supr-con↗
arXiv2012

Enhancement of superconducting properties in FeSe wires using a quenching technique

Enhancements of superconducting properties were observed in FeSe wires using a quenching technique. Zero resistivity was achieved at about 10 K in quenched wires, which is about 2 K higher than that of polycrystalline FeSe bulk. Furthermore, transport Jc of quenched wires showed three times higher than that of furnace-cooled wires. In contrast, the quenched polycrystalline FeSe bulks did not show the enhancement of Tc. The quenching technique is a greatly promising for fabricating FeSe wires with high Tc and high Jc, and quenched FeSe wires have high potential for superconducting wire applications.

cond-mat.supr-con↗
arXiv2011

Transport properties and microstructure of mono- and seven-core wires of FeSe1-xTex superconductor by Fe-diffusion powder-in-tube method

We report the successful fabrication of mono- and seven-core superconducting wires of FeSe1-xTex using an in-situ Fe-diffusion process based on the powder-in-tube (Fe-diffusion PIT) method. The reacted layer in these wires were found to have composite structure with composition nearly FeSe and FeTe for the inner and outer layers, although a single layer of composition FeSe0.5Te0.5 was supposed to be formed. The self-field transport Jc values at 4.2 K were found to be 226.2 A/cm2 and 100.3 A/cm2 respectively for mono- and seven-core wires. The Jc's of mono- and seven-core wires dropped rapidly at low fields and then showed a gradual decrease with increasing magnetic fields. In addition, the seven-core wire showed higher Jc than the mono-core wire under higher magnetic fields, indicating that the seven-core wire of FeSe1-xTex superconductor using Fe-diffusion PIT method is advantageous for the superconducting-wire application under high magnetic fields.

cond-mat.supr-con↗
arXiv2011

Electrochemical synthesis of iron-based superconductor FeSe films

The superconducting FeSe films were successfully fabricated using the electrochemical synthesis. The composition ratio of Fe and Se can be controlled by the electric potential and pH value. We found that the FeSe films deposited at the electric potential -1.75 V and pH 2.3 show the superconducting transition at 3.5 K. The establishment of this electrochemical synthesis technique will provide many advantages for application.

cond-mat.supr-con↗
arXiv2011

Preparation of Thin Crystals of FeTe1-xSx Using the Scotch-Tape Method

We have investigated an applicability of the scotch-tape method to fabricating thin crystals of Fe chalcogenide FeTe1-xSx. Thin crystals with a typical thickness of 40 nm were expectedly left on a Si substrate. Thin films prepared using this process will develop both detailed studies on intrinsic nature of Fe-based superconductivity and application to superconducting devices.

cond-mat.supr-con↗
arXiv2010

Transport properties of the new Fe-based superconductor KxFe2Se2 (Tc = 33 K)

We synthesized the new Fe-based superconductor K0.8Fe2Se2 single crystals. The obtained single crystal exhibited a sharp superconducting transition, and the onset and zero-resistivity temperature was estimated to be 33 and 31.8 K, respectively. A high upper critical field of 192 T was obtained. Anisotropy of superconductivity of K0.8Fe2Se2 was ~3.6. Both the high upper critical field and comparably low anisotropy are advantageous for the application under high magnetic field.

cond-mat.supr-con↗
arXiv2010

Single crystal growth and structural characterization of FeTe1-xSx

We have synthesized single crystals of FeTe1-xSx and investigated the structural and physical properties. The actual S concentration was found to be significantly smaller than the starting nominal value. The solubility limit of S for the Te site for the crystals grown using a self-flux method was estimated to be around 12 %. Although a suppression of antiferromagnetic transition was observed by S substitution, bulk superconductivity was not observed. A phase diagram of as-grown FeTe1-xSx single crystal was established on the basis of the structural and physical properties.

cond-mat.supr-con↗
arXiv2010

Superconductivity in oxygen-annealed FeTe1-xSx single crystal

We investigated the S-doping-driven phase transition from antiferromagnetic to superconducting in FeTe1-xSx single crystals. The partial substitution of Te by S suppresses antiferromagnetism in Fe-square lattice. Superconductivity is induced by oxygen annealing for only FeTe1-xSx in which the long-range magnetic ordering is suppressed. To realize superconductivity in FeTe1-xSx, both S concentration enough to suppress antiferromagnetism and oxygen annealing are required. Anisotropy of superconductivity in oxygen-annealed FeTe0.886S0.114 was estimated to be 1.17.

cond-mat.supr-con↗
arXiv2010

Moisture-induced superconductivity in FeTe0.8S0.2

Moisture-induced superconductivity was observed in FeTe0.8S0.2. With exposing the sample to the air, the zero resistivity temperature and the superconducting volume fraction were enhanced up to 7.2 K and 48.5 %, respectively, while the as-grown sample showed only filamentary superconductivity. We concluded that the causes of the evolution of superconductivity were water-related ions and/or molecules, because only the sample kept in water at room temperature for several days showed superconductivity. The speed of evolution of superconductivity was strongly enhanced by immersing the sample into the hot water.

cond-mat.supr-con↗
arXiv2010

Evolution of superconductivity by oxygen annealing in FeTe0.8S0.2

Oxygen annealing dramatically improved the superconducting properties of solid-state-reacted FeTe0.8S0.2, which showed only a broad onset of superconducting transition just after the synthesis. The zero resistivity appeared and reached 8.5 K by the oxygen annealing at 200\degree C. The superconducting volume fraction was also enhanced from 0 to almost 100%. The lattice constants were compressed by the oxygen annealing, indicating that the evolution of bulk superconductivity in FeTe0.8S0.2 was correlated to the shrinkage of lattice.

cond-mat.supr-con↗
arXiv2009

Mossbauer studies on FeSe and FeTe

We carried out 57Fe Mossbauer measurements for FeSe and Fe1.08Te to investigate the magnetic properties. There was no sign of magnetic ordering above 4.2 K for superconducting FeSe. The magnetic sextet corresponding to antiferromagnetic ordering of Fe in low-spin state was observed for non-superconducting Fe1.08Te.

cond-mat.supr-con↗
arXiv2009

Pressure effects on FeSe family superconductors

We investigated the pressure effects on the FeSe superconductor and the related compounds. Pressure dependence of superconducting transition temperature (Tc) for FeSe0.8S0.2 exhibits a dome-shaped behavior below 0.76 GPa. On the other hand, the Tc of FeSe0.25Te0.75 linearly increases up to 0.99 GPa. Here we discuss the relation between the physical pressure effects and the chemical pressure effects on the FeSe system.

cond-mat.supr-con↗
arXiv2009

Fabrication of the iron-based superconducting wire using Fe(Se, Te)

We have fabricated the Fe(Se, Te) superconducting wire by a special process based on a powder-in-tube method. The pure Fe tube plays the role of not only the sheath but also the raw material for synthesizing the superconducting phases. We succeeded in observing zero resistivity current on the current-voltage measurements for the Fe(Se, Te) wire. Introduction of the pinning centers and fabricating a multi-core wire will enhance the critical current density for the next step.

cond-mat.supr-con↗
arXiv2008

Superconductivity at 27 K in tetragonal FeSe under high pressure

A huge enhancement of the superconducting transition temperature Tc was observed in tetragonal FeSe superconductor under high pressure. The onset temperature became as high as 27 K at 1.48 GPa and the pressure coefficient showed a huge value of 9.1 K/GPa. The upper critical field Hc2 was estimated to be ~ 72 T at 1.48 GPa. Because of the high Hc2, FeSe system may be a candidate for application as superconducting wire rods. Moreover, the investigation of superconductivity on simple structured FeSe may provide important clues to the mechanism of superconductivity in iron-based superconductors.

cond-mat.supr-con↗
arXiv2008

Resistivity reduction of boron-doped multi-walled carbon nanotubes synthesized from a methanol solution containing a boric acid

Boron-doped multi-walled carbon nanotubes (MWNTs) were synthesized using a methanol solution of boric acid as a source material. Accurate measurements of the electrical resistivity of an individual boron-doped MWNT was performed with a four-point contact, which was fabricated using an electron beam lithography technique. The doped boron provides conduction carriers, which reduces the resistivity of the MWNT.

cond-mat.mtrl-sci↗