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Xiaojing Huang

Publications and source records attributed to Xiaojing Huang.

At least 37 records · Page 2Linked to original sources

Upcycling Low-Nickel Polycrystalline Cathodes from Retired Electric Vehicle Batteries into Single-Crystal Nickel-Rich Cathodes

The electrification revolution in automobile industry and others demands annual production capacity of batteries at least on the order of 102 gigawatts hours, which presents a twofold challenge to supply of key materials such as cobalt and nickel and to recycling when the batteries retire. Pyrometallurgical and hydrometallurgical recycling are currently used in industry but suffer from complexity, high costs, and secondary pollution. Here we report a direct-recycling method in molten salts (MSDR) that is environmentally benign and value-creating based on a techno-economic analysis using real-world data and price information. We also experimentally demonstrate the feasibility of MSDR by upcycling a low-nickel polycrystalline LiNi0.5Mn0.3Co0.2O2 (NMC) cathode material that is widely used in early-year electric vehicles into Ni-rich (Ni > 65%) single-crystal NMCs with increased energy-density (>10% increase) and outstanding electrochemical performance (>94% capacity retention after 500 cycles in pouch-type full cells). This work opens up new opportunities for closed-loop recycling of electric vehicle batteries and manufacturing of next-generation NMC cathode materials.

physics.app-ph↗

Proton distribution visualization in perovskite nickelate devices utilizing nanofocused X-rays

We use a 30-nm x-ray beam to study the spatially resolved properties of a SmNiO$_3$-based nanodevice that is doped with protons. The x-ray absorption spectra supported by density-functional theory (DFT) simulations show partial reduction of nickel valence in the region with high proton concentration, which leads to the insulating behavior. Concurrently, x-ray diffraction reveals only a small lattice distortion in the doped regions. Together, our results directly show that the knob which proton doping modifies is the electronic valency, and not the crystal lattice. The studies are relevant to on-going efforts to disentangle structural and electronic effects across metal-insulator phase transitions in correlated oxides.

cond-mat.mtrl-sci↗

Airplane-Aided Integrated Next-Generation Networking

A high-rate yet low-cost air-to-ground (A2G) communication backbone is conceived for integrating the space and terrestrial network by harnessing the opportunistic assistance of the passenger planes or high altitude platforms (HAPs) as mobile base stations (BSs) and millimetre wave communication. The airliners act as the network-provider for the terrestrial users while relying on satellite backhaul. Three different beamforming techniques relying on a large-scale planar array are used for transmission by the airliner/HAP for achieving a high directional gain, hence minimizing the interference among the users. Furthermore, approximate spectral efficiency (SE) and area spectral efficiency (ASE) expressions are derived and quantified for diverse system parameters.

eess.SP↗

Accurate Frequency Estimation with Fewer DFT Interpolations based on Padé Approximation

Frequency estimation is a fundamental problem in many areas. The well-known A&M and its variant estimators have established an estimation framework by iteratively interpolating the discrete Fourier transform (DFT) coefficients. In general, those estimators require two DFT interpolations per iteration, have uneven initial estimation performance against frequencies, and are incompetent for small sample numbers due to low-order approximations involved. Exploiting the iterative estimation framework of A&M, we unprecedentedly introduce the Padé approximation to frequency estimation, unveil some features about the updating function used for refining the estimation in each iteration, and develop a simple closed-form solution to solving the residual estimation error. Extensive simulation results are provided, validating the superiority of the new estimator over the state-the-art estimators in wide ranges of key parameters.

eess.SP↗

A Low-Complexity Method for FFT-based OFDM Sensing

OFDM sensing is gaining increasing popularity in wideband radar applications as well as in joint communication and radar/radio sensing (JCAS). As JCAS will potentially be integrated into future mobile networks where OFDM is crucial, OFDM sensing is envisioned to be ubiquitously deployed. A fast Fourier transform (FFT) based OFDM sensing (FOS) method was proposed a decade ago and has been regarded as a de facto standard given its simplicity. In this article, we introduce an easy trick -- a pre-processing on target echo -- to further reduce the computational complexity of FOS without degrading key sensing performance. Underlying the trick is a newly disclosed feature of the target echo in OFDM sensing which, to the best of our knowledge, has not been effectively exploited yet.

eess.SP↗

Scoring the Terabit/s Goal:Broadband Connectivity in 6G

This paper explores the road to vastly improving the broadband connectivity in future 6G wireless systems. Different categories of use cases are considered, with peak data rates up to 1 Tbps. Several categories of enablers at the infrastructure, spectrum, and protocol/algorithmic levels are required to realize the intended broadband connectivity goals in 6G. At the infrastructure level, we consider ultra-massive MIMO technology (possibly implemented using holographic radio), intelligent reflecting surfaces, user-centric cell-free networking, integrated access and backhaul, and integrated space and terrestrial networks. At the spectrum level, the network must seamlessly utilize sub-6 GHz bands for coverage and spatial multiplexing of many devices, while higher bands will be mainly used for pushing the peak rates of point-to-point links. Finally, at the protocol/algorithmic level, the enablers include improved coding, modulation, and waveforms to achieve lower latency, higher reliability, and reduced complexity.

eess.SP↗

Using a modified double deep image prior for crosstalk mitigation in multislice ptychography

Multislice ptychography is a high-resolution microscopy technique used to image multiple separate axial planes using a single illumination direction. However, multislice ptychography reconstructions are often degraded by crosstalk, where some features on one plane erroneously contribute to the reconstructed image of another plane. Here, we demonstrate the use of a modified "double deep image prior" (DDIP) architecture in mitigating crosstalk artifacts in multislice ptychography. Utilizing the tendency of generative neural networks to produce natural images, a modified DDIP method yielded good results on experimental data. For one of the datasets, we show that using DDIP could remove the need of using additional experimental data, such as from x-ray fluorescence, to suppress the crosstalk. Our method may help x-ray multislice ptychography work for more general experimental scenarios.

eess.IV↗

Adorym: A multi-platform generic x-ray image reconstruction framework based on automatic differentiation

We describe and demonstrate an optimization-based x-ray image reconstruction framework called Adorym. Our framework provides a generic forward model, allowing one code framework to be used for a wide range of imaging methods ranging from near-field holography to and fly-scan ptychographic tomography. By using automatic differentiation for optimization, Adorym has the flexibility to refine experimental parameters including probe positions, multiple hologram alignment, and object tilts. It is written with strong support for parallel processing, allowing large datasets to be processed on high-performance computing systems. We demonstrate its use on several experimental datasets to show improved image quality through parameter refinement.

eess.IV↗

Low-Complexity Frequency Domain Equalization over Fast Fading Channels

Wireless communications over fast fading channels are challenging, requiring either frequent channel tracking or complicated signaling schemes such as orthogonal time frequency space (OTFS) modulation. In this paper, we propose low-complexity frequency domain equalizations to combat fast fading, based on novel discrete delay-time and frequency-Doppler channel models. Exploiting the circular stripe diagonal nature of the frequency-Doppler channel matrix, we introduce low-complexity frequency domain minimum mean square error (MMSE) equalization for OTFS systems with fully resolvable Doppler spreads. We also demonstrate that the proposed MMSE equalization is applicable to conventional orthogonal frequency division multiplexing (OFDM) and single carrier frequency domain equalization (SC-FDE) systems with short signal frames and partially resolvable Doppler spreads. After generalizing the input-output data symbol relationship, we analyze the equalization performance via channel matrix eigenvalue decomposition and derive a closed-form expression for the theoretical bit-error-rate. Simulation results for OTFS, OFDM, and SC-FDE modulations verify that the proposed low-complexity frequency domain equalization methods can effectively exploit the time diversity over fast fading channels. Even with partially resolvable Doppler spread, the conventional SC-FDE can achieve performance close to OTFS, especially in fast fading channels with a dominating line-of-sight path.

cs.IT↗

Waveform Optimization with Multiple Performance Metrics for Broadband Joint Communication and Radar Sensing

Joint communication and radar sensing (JCAS) integrates communication and radar/radio sensing into one system, sharing one transmitted signal. In this paper, we investigate JCAS waveform optimization underlying communication signals, where a base station detects radar targets and communicates with mobile users simultaneously. We first develop individual novel waveform optimization problems for communications and sensing, respectively. For communications, we propose a novel lower bound of sum rate by integrating multi-user interference and effective channel gain into one metric that simplifies the optimization of the sum rate. For radar sensing, we consider optimizing one of two metrics, the mutual information or the Cramer-Rao bound. Then, we formulate the JCAS problem by optimizing the communication metric under different constraints of the radar metric, and we obtain both closed-form solutions and iterative solutions to the non-convex JCAS optimization problem. Numerical results are provided and verify the proposed optimization solutions.

eess.SP↗

Uplink Sensing in Perceptive Mobile Networks with Asynchronous Transceivers

Perceptive mobile network (PMN) is a recently proposed next-generation network that integrates radar sensing into communication. One major challenge for realizing sensing in PMNs is how to deal with spatially-separated asynchronous transceivers. The asynchrony between sensing receiver and transmitter will cause both timing offsets (TOs) and carrier frequency offsets (CFOs) and lead to degraded sensing accuracy in both ranging and velocity measurements. In this paper, we propose an uplink sensing scheme for PMNs with asynchronous transceivers, targeting at resolving the sensing ambiguity and improving the sensing accuracy. We first adopt a cross-antenna cross-correlation (CACC) operation to remove the sensing ambiguity associated with both TOs and CFOs. Without sensing ambiguity, both actual propagation delay and actual Doppler frequency of multiple targets can be obtained using CACC outputs. To exploit the redundancy of the CACC outputs and reduce the complexity, we then propose a novel mirrored-MUSIC algorithm, which halves the number of unknown parameters to be estimated, for obtaining actual values of delays and Doppler frequencies. Finally, we propose a high-resolution angles-of-arrival (AoAs) estimation algorithm, which jointly processes all measurements from spatial, temporal, and frequency domains. The proposed AoAs estimation algorithm can achieve significantly higher estimation accuracy than that of using samples from the spatial domain only. We also derive the theoretical mean-square-error of the proposed algorithms. Numerical results are provided and validate the effectiveness of the proposed scheme.

eess.SP↗

Frequency-Hopping MIMO Radar-Based Communications: An Overview

Enabled by the advancement in radio frequency technologies, the convergence of radar and communication systems becomes increasingly promising and is envisioned as a key feature of future 6G networks. Recently, the frequency-hopping (FH) MIMO radar is introduced to underlay dual-function radar-communication (DFRC) systems. Superior to many previous radar-centric DFRC designs, the symbol rate of FH-MIMO radar-based DFRC (FH-MIMO DFRC) can exceed the radar pulse repetition frequency. However, many practical issues, particularly those regarding effective data communications, are unexplored/unsolved. To promote the awareness and general understanding of the novel DFRC, this article is devoted to providing a timely introduction of FH-MIMO DFRC. We comprehensively review many essential aspects of the novel DFRC: channel/signal models, signaling strategies, modulation/demodulation processing and channel estimation methods, to name a few. We also highlight major remaining issues in FH-MIMO DFRC and suggest potential solutions to shed light on future research works.

eess.SP↗

Integrating Secure and High-Speed Communications into Frequency Hopping MIMO Radar

Dual-function radar-communication (DFRC) based on frequency hopping (FH) MIMO radar (FH-MIMO DFRC) achieves symbol rate much higher than radar pulse repetition frequency. Such DFRC, however, is prone to eavesdropping due to the spatially uniform illumination of FH-MIMO radar. How to enhance the physical layer security of FH-MIMO DFRC is vital yet unsolved. In this paper, we reveal the potential of using permutations of hopping frequencies to achieve secure and high-speed FH-MIMO DFRC. Detecting permutations at a communication user is challenging due to the dependence on spatial angle. We propose a series of baseband waveform processing methods which address the challenge specifically for the legitimate user (Bob) and meanwhile scrambles constellations almost omnidirectionally. We discover a deterministic sign rule from the signals processed by the proposed methods. Based on the rule, we develop accurate algorithms for information decoding at Bob. Confirmed by simulation, our design achieves substantially high physical layer security for FH-MIMO DFRC, improves decoding performance compared with existing designs and reduces mutual interference among radar targets.

eess.SP↗

Waveform Design and Accurate Channel Estimation for Frequency-Hopping MIMO Radar-Based Communications

Frequency-hopping (FH) MIMO radar-based dual-function radar communication (FH-MIMO DFRC) enables communication symbol rate to exceed radar pulse repetition frequency, which requires accurate estimations of timing offset and channel parameters. The estimations, however, are challenging due to unknown, fast-changing hopping frequencies and the multiplicative coupling between timing offset and channel parameters. In this paper, we develop accurate methods for a single-antenna communication receiver to estimate timing offset and channel for FH-MIMO DFRC. First, we design a novel FH-MIMO radar waveform, which enables a communication receiver to estimate the hopping frequency sequence (HFS) used by radar, instead of acquiring it from radar. Importantly, the novel waveform incurs no degradation to radar ranging performance. Then, via capturing distinct HFS features, we develop two estimators for timing offset and derive mean squared error lower bound of each estimator. Using the bounds, we design an HFS that renders both estimators applicable. Furthermore, we develop an accurate channel estimation method, reusing the single hop for timing offset estimation. Validated by simulations, the accurate channel estimates attained by the proposed methods enable the communication performance of DFRC to approach that achieved based on perfect timing and ideal knowledge of channel.

eess.SP↗

Complete Strain Mapping of Nanosheets of Tantalum Disulfide

Quasi-two-dimensional (quasi-2D) materials hold promise for future electronics because of their unique band structures that result in electronic and mechanical properties sensitive to crystal strains in all three dimensions. Quantifying crystal strain is a prerequisite to correlating it with the performance of the device, and calls for high resolution but spatially resolved rapid characterization methods. Here we show that using fly-scan nano X-ray diffraction we can accomplish a tensile strain sensitivity below 0.001% with a spatial resolution of better than 80 nm over a spatial extent of 100 $μ$m on quasi 2D flakes of 1T-TaS2. Coherent diffraction patterns were collected from a $\sim$ 100 nm thick sheet of 1T-TaS2 by scanning 12keV focused X-ray beam across and rotating the sample. We demonstrate that the strain distribution around micron and sub-micron sized 'bubbles' that are present in the sample may be reconstructed from these images. The experiments use state of the art synchrotron instrumentation, and will allow rapid and non-intrusive strain mapping of thin film samples and electronic devices based on quasi 2D materials.

cond-mat.mtrl-sci↗

Spatially correlated incommensurate lattice modulations in an atomically thin high-temperature Bi_{2.1}Sr_{1.9}CaCu_{2.0}O_{8+δ} superconductors

Strong variations in superconducting critical temperatures in different families of the cuprate perovskites, even with similar hole doping in their copper-oxygen planes, suggest the importance of lattice modulation effects. The one-dimensional incommensurate lattice modulation (ILM) of Bi_2Sr_2CaCu_2O_{8+y}, with the average atomic positions perturbed beyond the unit cell, offers an ideal test ground for studying the interplay between superconductivity and the long-range incommensurate lattice fluctuations. Here we report Scanning nano X-ray Diffraction (SnXRD) imaging of incommensurate lattice modulations in Bi_{2.1}Sr_{1.9}CaCu_{2.0}O_{8+δ} Van der Waals heterostructures of thicknesses down to two-unit cells. Using SnXRD, we probe that the long-range and short-range incommensurate lattice modulations in bulk sample surface with spatial resolution below 100 nm. We find that puddle-like domains of ILM of size uniformly evolving with dimensionality. In the 2-unit cell thin sample, it is observed that the wavevectors of the long- and short-range orders become anti-correlated with emerging spatial patterns having a directional gradient. The emerging patterns, originated by tiny tuning of lattice strain, induce static mesoscopic charge density waves. Our findings thus demonstrate that the strain can be used to tune and control the electromagnetic properties of two-dimensional high-temperature superconductors.

cond-mat.mtrl-sci↗

White Paper on Broadband Connectivity in 6G

This white paper explores the road to implementing broadband connectivity in future 6G wireless systems. Different categories of use cases are considered, from extreme capacity with peak data rates up to 1 Tbps, to raising the typical data rates by orders-of-magnitude, to support broadband connectivity at railway speeds up to 1000 km/h. To achieve these goals, not only the terrestrial networks will be evolved but they will also be integrated with satellite networks, all facilitating autonomous systems and various interconnected structures. We believe that several categories of enablers at the infrastructure, spectrum, and protocol/ algorithmic levels are required to realize the intended broadband connectivity goals in 6G. At the infrastructure level, we consider ultra-massive MIMO technology (possibly implemented using holographic radio), intelligent reflecting surfaces, user-centric and scalable cell-free networking, integrated access and backhaul, and integrated space and terrestrial networks. At the spectrum level, the network must seamlessly utilize sub-6 GHz bands for coverage and spatial multiplexing of many devices, while higher bands will be used for pushing the peak rates of point-to-point links. The latter path will lead to THz communications complemented by visible light communications in specific scenarios. At the protocol/algorithmic level, the enablers include improved coding, modulation, and waveforms to achieve lower latencies, higher reliability, and reduced complexity. Different options will be needed to optimally support different use cases. The resource efficiency can be further improved by using various combinations of full-duplex radios, interference management based on rate-splitting, machine-learning-based optimization, coded caching, and broadcasting.

eess.SP↗

Multibeam Optimization for Joint Communication and Radio Sensing Using Analog Antenna Arrays

Multibeam technology enables the use of two or more subbeams for joint communication and radio sensing, to meet different requirements of beamwidth and pointing directions. Generating and optimizing multibeam subject to the requirements is critical and challenging, particularly for systems using analog arrays. This paper develops optimal solutions to a range of multibeam design problems, where both communication and sensing are considered. We first study the optimal combination of two pre-generated subbeams, and their beamforming vectors, using a combining phase coefficient. Closed-form optimal solutions are derived to the constrained optimization problems, where the received signal powers for communication and the beamforming waveforms are alternatively used as the objective and constraint functions. We also develop global optimization methods which directly find optimal solutions for a single beamforming vector. By converting the original intractable complex NP-hard global optimization problems to real quadratically constrained quadratic programs, near-optimal solutions are obtained using semidefinite relaxation techniques. Extensive simulations validate the effectiveness of the proposed constrained multibeam generation and optimization methods.

eess.SP↗