arXiv subjects

Y. Tokura

Publications and source records attributed to Y. Tokura.

At least 253 records · Page 14Linked to original sources

arXiv2007

Optical phase diagram of perovskite-type colossal magnetoresistance manganites with near-half doping

We present a systematic optical study for a bandwidth-controlled series of nearly half doped colossal magnetoresistive manganites RE$_{0.55}$AE$_{0.45}$MnO$_3$ (RE and AE being rare earth and alkaline earth ions, respectively) under the presence of quenched disorder over a broad temperature region $T=10-800$ K. The ground state of the compounds ranges from the charge and orbital ordered insulator through the spin glass to the ferromagnetic metal. The enhanced phase fluctuations, namely the short-range charge and orbital correlations dominate the paramagnetic region of the phase diagram above all the ground-state phases. This paramagnetic region is characterized by a full-gap to pseudo-gap crossover towards elevated temperatures where a broad low-energy electronic structure appears in the conductivity spectra over a large variation of the bandwidth. This pseudo-gap state with local correlations is robust against thermal fluctuations at least up to T=800 K. For small bandwidth the onset of the long-range charge order is accompanied by an instantaneous increase of the gap. The emergence of the ferromagnetic state is manifested in the optical spectra as a first-order insulator to metal transition for compounds with moderate bandwidth while it becomes a second-order transition on the larger bandwidth side. Unusually large scattering rate of the metallic carriers is observed in the ferromagnetic state which is attributed to orbital correlation with probably rod-like ($3z^2-r^2$-like) character.

cond-mat.str-el↗

arXiv2007

The nanoscale phase separation in hole-doped manganites

A macroscopic phase separation, in which ferromagnetic clusters are observed in an insulating matrix, is sometimes observed, and believed to be essential to the colossal magnetoresistive (CMR) properties of manganese oxides. The application of a magnetic field may indeed trigger large magnetoresistance effects due to the percolation between clusters allowing the movement of the charge carriers. However, this macroscopic phase separation is mainly related to extrinsic defects or impurities, which hinder the long-ranged charge-orbital order of the system. We show in the present article that rather than the macroscopic phase separation, an homogeneous short-ranged charge-orbital order accompanied by a spin glass state occurs, as an intrinsic result of the uniformity of the random potential perturbation induced by the solid solution of the cations on the $A$-sites of the structure of these materials. Hence the phase separation does occur, but in a more subtle and interesting nanoscopic form, here referred as ``homogeneous''. Remarkably, this ``nanoscale phase separation'' alone is able to bring forth the colossal magnetoresistance in the perovskite manganites, and is potentially relevant to a wide variety of other magnetic and/or electrical properties of manganites, as well as many other transition metal oxides, in bulk or thin film form as we exemplify throughout the article.

cond-mat.mtrl-sci↗

arXiv2007

Orbital Domain Dynamics in a Doped Manganite

The coupling of multiple degrees of freedom - charge, spin, and lattice - in manganites has mostly been considered at the microscopic level. However, on larger length scales, these correlations may be affected by strain and disorder, which can lead to short range order in these phases and affect the coupling between them. To better understand these effects, we explore the dynamics of orbitally ordered domains in a half-doped manganite near the orbital ordering phase transition. Our results suggest that the domains are largely static, and exhibit only slow fluctuations near domain boundaries.

cond-mat.str-el↗

arXiv2007

Electron spin manipulation and resonator readout in a double quantum dot nano-electromechanical system

Magnetically coupling a nano-mechanical resonator to a double quantum dot confining two electrons can enable the manipulation of a single electron spin and the readout of the resonator's natural frequency. When the Larmor frequency matches the resonator frequency, the electron spin in one of the dots can be selectively flipped by the magnetised resonator. By simultaneously measuring the charge state of the two-electron double quantum dots, this transition can be detected thus enabling the natural frequency of the mechanical resonator to be determined.

cond-mat.mes-hall↗

arXiv2007

Coexistence of long-ranged charge and orbital order and spin-glass state in single-layered manganites with weak quenched disorder

The relationship between orbital and spin degrees of freedom in the single-crystals of the hole-doped Pr$_{1-x}$Ca$_{1+x}$MnO$_4$, 0.3 $\leq$ $x$ $\leq$ 0.7, has been investigated by means of ac-magnetometry and charge transport. Even though there is no cation ordering on the $A$-site, the quenched disorder is extremely weak in this system due to the very similar ionic size of Pr$^{3+}$ and Ca$^{2+}$. A clear asymmetric response of the system to the under- (respective over-) hole doping was observed. The long-ranged charge-orbital order established for half doping ($x$=0.5) subsists in the over-doping case ($x$ $>$ 0.5), albeit rearranged to accommodate the extra holes introduced in the structure. The charge-orbital order is however destabilized by the presence of extra localized electrons (under-doping, $x$ $<$ 0.5), leading to its disappearance below $x$=0.35. We show that in an intermediate under-doped region, with 0.35 $\leq$ $x$ $<$ 0.5, the ``orbital-master spin-slave'' relationship commonly observed in half-doped manganites does not take place. The long-ranged charge-orbital order is not accompanied by an antiferromagnetic transition at low temperatures, but by a frustrated short-ranged magnetic state bringing forth a spin-glass phase. We discuss in detail the nature and origin of this spin-glass state, which, as in the half-doped manganites with large quenched disorder, is not related to the macroscopic phase separation observed in crystals with minor defects or impurities.

cond-mat.mtrl-sci↗

arXiv2007

Local Tunneling Spectroscopy across a Metamagnetic Critical Point in the Bi-layer Ruthenate Sr3Ru2O7

The local spectroscopic signatures of metamagnetic criticality in Sr3Ru2O7 were explored using scanning tunneling microscopy (STM). Singular features in the tunneling spectrum were found close to the Fermi level, as would be expected in a Stoner picture of itinerant electron metamagnetism. These features showed a pronounced magnetic field dependence across the metamagnetic critical point, which cannot be understood in terms of a naive Stoner theory. In addition, a pseudo-gap structure was observed over several tens of meV, accompanied by a c(2x2) superstructure in STM images. This result represents a new electronic ordering at the surface in the absence of any measurable surface reconstruction.

cond-mat.str-el↗

arXiv2007

Temperature-dependent photoemission spectral weight transfer and chemical potential shift in Pr$_{1-x}$Ca$_x$MnO$_3$ : Implications for charge density modulation

We have studied the temperature dependence of the photoemission spectra of Pr$_{1-x}$Ca$_x$MnO$_3$ (PCMO) with $x=0.25$, 0.3 and 0.5. For $x=0.3$ and 0.5, we observed a gap in the low-temperature CE-type charge-ordered (CO) phase and a pseudogap with a finite intensity at the Fermi level ($E_F$) in the high-temperature paramagnetic insulating (PI) phase. Within the CO phase, the spectral intensity near $E_F$ gradually increased with temperature. These observations are consistent with the results of Monte Carlo simulations on a model including charge ordering and ferromagnetic fluctuations [H. Aliaga {\it et al.} Phys. Rev. B {\bf 68}, 104405 (2003)]. For $x=0.25$, on the other hand, little temperature dependence was observed within the low-temperature ferromagnetic insulating (FI) phase and the intensity at $E_F$ remained low in the high-temperature PI phase. We attribute the difference in the temperature dependence near $E_F$ between the CO and FI phases to the different correlation lengths of orbital order between both phases. Furthermore, we observed a chemical potential shift with temperature due to the opening of the gap in the FI and CO phases. The doping dependent chemical potential shift was recovered at low temperatures, corresponding to the disappearance of the doping dependent change of the modulation wave vector. Spectral weight transfer with hole concentration was clearly observed at high temperatures but was suppressed at low temperatures. We attribute this observation to the fixed periodicity with hole doping in PCMO at low temperatures.

cond-mat.str-el↗

arXiv2007

Effect of antiferromagnetic spin correlations on lattice distortion and charge ordering in Pr$_{0.5}$Ca$_{1.5}$MnO$_{4}$

We use neutron scattering to study the lattice and magnetic structure of the layered half-doped manganite Pr$_{0.5}$Ca$_{1.5}$MnO$_4$. On cooling from high temperature, the system first becomes charge- and orbital- ordered (CO/OO) near $T_{CO}=300$ K and then develops checkerboard-like antiferromagnetic (AF) order below $T_{N}=130$ K. At temperatures above $T_{N}$ but below $T_{CO}$ ($T_N<T<T_{CO}$), the appearance of short-range AF spin correlations suppresses the CO/OO induced orthorhombic strain, contrasting with other half-doped manganites, where AF order has no observable effect on the lattice distortion. These results suggest that a strong spin-lattice coupling and the competition between AF exchange and CO/OO ordering ultimately determines the low-temperature properties of the system.

cond-mat.str-el↗

arXiv2007

Logarithmic growth law in the two-dimensional Ising spin glass state resulting from the electron doping in single-layered manganites

The ac-susceptibility of the electron doped single-layered manganite La$_{1.1}$Sr$_{0.9}$MnO$_4$ is analyzed in detail. A quasi two-dimensional (2$D$) antiferromagnetic (AFM) order with Ising anisotropy is stabilized below $T_N$ $\sim$ 80K. We show that below $T_N$, a rare 2$D$ spin-glass (SG) correlation develops with the same Ising anisotropy as the AFM state. Using simple scaling arguments of the droplet model, we derive a scaling form for the ac-susceptibility data of a 2$D$ SG, which our experimental data follows fairly well. Due to simplifications in this 2$D$ case, the proposed scaling form only contains two unknown variables $ψν$ and $τ_0$. Hence, the logarithmic growth law of the SG correlation predicted by the droplet model is convincingly evidenced by the scaling of our experimental data. The origin and nature of this 2$D$ SG state is also discussed.

cond-mat.mtrl-sci↗

arXiv2007

Quantum criticality and disorder in the antiferromagnetic critical point of NiS$_{2}$ pyrite

A quantum critical point (QCP) between the antiferromagnetic and the paramagnetic phases was realized by applying a hydrostatic pressure of ~ 7 GPa on single crystals of NiS_{2} pyrite with a low residual resistivity, rho_{0}, of 0.5 mu-Omega-cm. We found that the critical behavior of the resistivity, rho, in this clean system contrasts sharply with those observed in its disordered analogue, NiS_{2-x}Se_{x} solid-solution, demonstrating the unexpectedly drastic effect of disorder on the quantum criticality. Over a whole paramagnetic region investigated up to P = 9 GPa, a crossover temperature, defined as the onset of T^{2} dependence of rho, an indication of Fermi liquid, was suppressed to a substantially low temperature T sim 2 K and, instead, a non Fermi liquid behavior of rho, T^{3/2}-dependence, robustly showed up.

cond-mat.str-el↗

arXiv2007

Resonance in Optimally Electron-Doped Superconductor Nd$_{1.85}$Ce$_{0.15}$CuO$_{4-δ}$

We use inelastic neutron scattering to probe magnetic excitations of an optimally electron-doped superconductor Nd$_{1.85}$Ce$_{0.15}$CuO$_{4-δ}$ above and below its superconducting transition temperature $T_c=25$ K. In addition to gradually opening a spin pseudo gap at the antiferromagnetic ordering wavevector ${\bf Q}=(1/2,1/2,0)$, the effect of superconductivity is to form a resonance centered also at ${\bf Q}=(1/2,1/2,0)$ but at energies above the spin pseudo gap. The intensity of the resonance develops like a superconducting order parameter, similar to those for hole-doped superconductors and electron-doped Pr$_{0.88}$LaCe$_{0.12}$CuO$_4$. The resonance is therefore a general phenomenon of cuprate superconductors, and must be fundamental to the mechanism of high-$T_c$ superconductivity.

cond-mat.supr-con↗

arXiv2007

Variation of charge/orbital ordering in layered manganites Pr1-xCa1+xMnO4 investigated by transmission electron microscopy

Structural features of the charge/orbital ordering (CO/OO) in single-layered manganites Pr1-xCa1+xMnO4 have been investigated systematically by transmission electron microscopy. Analyses of electron diffraction patterns as well as dark-field images have revealed that the CO/OO shows a striking asymmetric behavior as the hole doping x deviates from x = 0.5. The modulation wavenumber linearly decreases with increasing x in the over-hole-doped (x > 0.5) crystals, while much less dependent on x in the under-hole-doped (x < 0.5) crystals. A temperature-induced incommensurate-commensurate crossover is observed in 0.35 < x < 0.5 and x = 0.65. The correlation length of CO/OO in x = 0.3 was proven to become shorter than that in x > 0.3.

cond-mat.str-el↗

arXiv2007

Spin waves throughout the Brillouin zone and magnetic exchange coupling in ferromagnetic metallic manganites La$_{1-x}$Ca$_{x}$MnO$_3$ ($x=0.25,0.30$)

Using time-of-flight and triple-axis inelastic neutron spectroscopy, we determine spin wave excitations throughout the Brillouin zone for ferromagnetic manganites La$_{1-x}$Ca$_x$MnO$_3$ ($x=0.25,0.3$) in their low temperature metallic states. While spin wave excitations in the long wavelength limit (spin stiffness $D$) have similar values for both compounds, the excitations near the Brillouin zone boundary of La$_{0.7}$Ca$_{0.3}$MnO$_3$ are considerable softened in all symmetry directions compared to that of La$_{0.75}$Ca$_{0.25}$MnO$_3$. A Heisenberg model with the nearest neighbor and the fourth neighbor exchange interactions can describe the overall dispersion curves fairly well. We compare the data with various theoretical models describing the spin excitations of ferromagnetic manganites.

cond-mat.str-el↗

arXiv2007

Optical probe of electrostatic doping in an n-type Mott insulator

Electrostatic doping into an $n$-type Mott insulator Sm$_{2}$CuO$_{4}$ has been successfully achieved with use of the heterojunction with an $n$-type band semiconductor Nb-doped SrTiO$_{3}$. The junction exhibits rectifying current-voltage characteristics due to the interface band discontinuity and the formation of depleted region. The application of reverse bias electric field on this junction enables the field-effect electron doping (presumably up to 6% per Cu atom) to the Mott insulator. The electro-modulation absorption spectroscopy could clearly show a large modification of the Mott-gap state accompanying the spectral weight transfer to the lower-energy region, reminiscent of formation of a metallic state.

cond-mat.str-el↗

arXiv2007

A hidden constant in the anomalous Hall effect of a high-purity magnet MnSi

Measurements of the Hall conductivity in MnSi can provide incisive tests of theories of the anomalous Hall (AH) effect, because both the mean-free-path and magnetoresistance (MR) are unusually large for a ferromagnet. The large MR provides an accurate way to separate the AH conductivity $σ_{xy}^A$ from the ordinary Hall conductivity $σ_{xy}^N$. Below the Curie temperature $T_C$, $σ_{xy}^A$ is linearly proportional to $ M$ (magnetization) with a proportionality constant $S_H$ that is independent of both $T$ and $H$. In particular, $S_H$ remains a constant while $σ_{xy}^N$ changes by a factor of 100 between 5 K and $T_C$. We discuss implications of the hidden constancy in $S_H$.

cond-mat.str-el↗

arXiv2007

Electric Control of Spin Helicity in a Magnetic Ferroelectric

Magnetic ferroelectrics or multiferroics, which are currently extensively explored, may provide a good arena to realize a novel magnetoelectric function. Here we demonstrate the genuine electric control of the spiral magnetic structure in one of such magnetic ferroelectrics, TbMnO3. A spin-polarized neutron scattering experiment clearly shows that the spin helicity, clockwise or counter-clockwise, is controlled by the direction of spontaneous polarization and hence by the polarity of the small cooling electric field.

cond-mat.str-el↗

arXiv2006

Micro-magnets for coherent control of spin-charge qubit in lateral quantum dots

A lateral quantum dot design for coherent electrical manipulation of a two-level spin-charge system is presented. Two micron-size permanent magnets integrated to high-frequency electrodes produce a static slanting magnetic field suitable for voltage controlled single qubit gate operations. Stray field deviation from the slanting form is taken into account in the Hamiltonian describing the two-level system, which involves hybridization of a single electron spin to the quantum dot's orbitals. Operation speed and gate fidelity are related to device parameters. Sub 100 ns $π$ pulse duration can be achieved with lattice fluctuations coherence time of 4 ms for GaAs.

cond-mat.mes-hall↗

arXiv2006

Impurity-doping induced ferroelectricity in frustrated antiferromagnet CuFeO2

Dielectric responses have been investigated on the triangular-lattice antiferromagnet CuFeO2 and its site-diluted analogs CuFe1-xAlxO2 (x=0.01 and 0.02) with and without application of magnetic field. We have found a ferroelectric behavior at zero magnetic field for x=0.02. At any doping level, the onset field of the ferroelectricity always coincides with that of the noncollinear magnetic structure while the transition field dramatically decreases to zero field with Al doping. The results imply the further possibility of producing the ferroelectricity by modifying the frustrated spin structure in terms of site-doping and external magnetic field.

cond-mat.str-el↗