arXiv subjects

J. -M. Triscone

Publications and source records attributed to J. -M. Triscone.

At least 19 recordsLinked to original sources

arXiv2022

Coupling of Magnetic Phases at Nickelate Interfaces

In this work we present a model system built out of artificially layered materials, allowing us to understand the interrelation of magnetic phases with that of the metallic-insulating phase at long length-scales, and enabling new strategies for the design and control of materials in devices. The artificial model system consists of superlattices made of SmNiO$_3$ and NdNiO$_3$ layers -- two members of the fascinating rare earth nickelate family, having different metal-to-insulator and magnetic transition temperatures. By combining two complementary techniques -- resonant elastic x-ray scattering and muon spin relaxation -- we show how the magnetic order evolves, in this complex multicomponent system, as a function of temperature and superlattice periodicity. We demonstrate that the length scale of the coupling between the antiferromagnetic and paramagnetic phases is longer than that of the electronic metal-insulator phase transition -- despite being subsidiary to it. This can be explained via a Landau theory -- where the bulk magnetic energy plus a gradient cost between magnetic and non magnetic phases are considered. These results provide a clear understanding of the coupling of magnetic transitions in systems sharing identical order parameters.

cond-mat.str-el↗

arXiv2020

Optical properties of LaNiO3 films tuned from compressive to tensile strain

Materials with strong electronic correlations host remarkable -- and technologically relevant -- phenomena such as magnetism, superconductivity and metal-insulator transitions. Harnessing and controlling these effects is a major challenge, on which key advances are being made through lattice and strain engineering in thin films and heterostructures, leveraging the complex interplay between electronic and structural degrees of freedom. Here we show that the electronic structure of LaNiO3 can be tuned by means of lattice engineering. We use different substrates to induce compressive and tensile biaxial epitaxial strain in LaNiO3 thin films. Our measurements reveal systematic changes of the optical spectrum as a function of strain and, notably, an increase of the low-frequency free carrier weight as tensile strain is applied. Using density functional theory (DFT) calculations, we show that this apparently counter-intuitive effect is due to a change of orientation of the oxygen octahedra.The calculations also reveal drastic changes of the electronic structure under strain, associated with a Fermi surface Lifshitz transition. We provide an online applet to explore these effects. The experimental value of integrated spectral weight below 2 eV is significantly (up to a factor of 3) smaller than the DFT results, indicating a transfer of spectral weight from the infrared to energies above 2 eV. The suppression of the free carrier weight and the transfer of spectral weight to high energies together indicate a correlation-induced band narrowing and free carrier mass enhancement due to electronic correlations. Our findings provide a promising avenue for the tuning and control of quantum materials employing lattice engineering.

cond-mat.str-el↗

arXiv2020

Probing photo-induced rearrangements in the NdNiO$_{3}$ magnetic spiral with polarization-sensitive ultrafast resonant soft x-ray scattering

We use resonant soft X-ray diffraction to track the photo-induced dynamics of the antiferromagnetic structure in a NdNiO$_{3}$ thin film. Femtosecond laser pulses with a photon energy of 0.61 eV, resonant with electron transfer between long-bond and short-bond nickel sites, are used to excite the material and drive an ultrafast insulator-metal transition. Polarization sensitive soft X-ray diffraction, resonant to the nickel L$_{3}$-edge, then probes the evolution of the underlying magnetic spiral as a function of time delay with 80 picosecond time resolution. By modelling the azimuthal dependence of the scattered intensity for different linear X-ray polarizations, we benchmark the changes of the local magnetic moments and the spin alignment. The measured changes are consistent with a reduction of the long-bond site magnetic moments and an alignment of the spins towards a more collinear structure at early time delays.

cond-mat.str-el↗

arXiv2017

Modulation of the superconducting critical temperature due to quantum confinement at the LaAlO$_3$/SrTiO$_3$ interface

Superconductivity develops in bulk doped SrTiO$_3$ and at the LaAlO$_3$/SrTiO$_3$ interface with a dome-shaped density dependence of the critical temperature $T_c$, despite different dimensionalities and geometries. We propose that the $T_c$ dome of LaAlO$_3$/SrTiO$_3$ is a shape resonance due to quantum confinement of superconducting bulk SrTiO$_3$. We substantiate this interpretation by comparing the exact solutions of a three-dimensional and quasi-two-dimensional two-band BCS gap equation. This comparison highlights the role of heavy bands for $T_c$ in both geometries. For bulk SrTiO$_3$, we extract the density dependence of the pairing interaction from the fit to experimental data. We apply quantum confinement in a square potential well of finite depth and calculate $T_c$ in the confined configuration. We compare the calculated $T_c$ to transport experiments and provide an explanation as to why the optimal $T_c$'s are so close to each other in two-dimensional interfaces and the three-dimensional bulk material.

cond-mat.supr-con↗

arXiv2016

Multiple supersonic phase fronts launched at a complex-oxide hetero-interface

Selective optical excitation of a substrate lattice can drive phase changes across hetero-interfaces. This phenomenon is a non-equilibrium analogue of static strain control in heterostructures and may lead to new applications in optically controlled phase change devices. Here, we make use of time-resolved non-resonant and resonant x-ray diffraction to clarify the underlying physics, and to separate different microscopic degrees of freedom in space and time. We measure the dynamics of the lattice and that of the charge disproportionation in NdNiO3, when an insulator-metal transition is driven by coherent lattice distortions in the LaAlO3 substrate. We find that charge redistribution propagates at supersonic speeds from the interface into the NdNiO3 film, followed by a sonic lattice wave. When combined with measurements of magnetic disordering and of the metal-insulator transition, these results establish a hierarchy of events for ultrafast control at complex oxide hetero-interfaces.

cond-mat.str-el↗

arXiv2016

Large phonon-drag enhancement induced by narrow quantum confinement at the LaAlO3/SrTiO3 interface

The thermoelectric power of the two-dimensional electron system (2DES) at the LaAlO3/SrTiO3 interface is explored below room temperature, in comparison with that of Nb-doped SrTiO3 single crystals. For the interface we find a region below T =50 K where thermopower is dominated by phonon-drag, whose amplitude is hugely amplified with respect to the corresponding bulk value, reaching values ~mV/K and above. The phonon-drag enhancement at the interface is traced back to the tight carrier confinement of the 2DES, and represents a sharp signature of strong electron-acoustic phonon coupling at the interface.

cond-mat.str-el↗

arXiv2016

Broadband THz spectroscopy of the insulator-metal transition driven by coherent lattice deformation at the SmNiO3/LaAlO3 interface

We investigate the non-equilibrium insulator-metal transition driven in a SmNiO3 thin film by coherent optical excitation of the LaAlO3 substrate lattice. By probing the transient optical properties over a broad frequency range (100 - 800 cm^-1), we analyze both the time dependent metallic plasma and the infrared optical phonon line shapes. We show that the light-induced metallic phase in SmNiO3 has the same carrier density as the equilibrium metallic phase. We also report that the LaAlO3 substrate acts as a transducer only at the earlier time delays, as the vibrations are driven coherently. No long-lived structural rearrangement takes place in the substrate. Finally, we show that the transient insulator-metal transition occurs both below and above the Néel temperature. We conclude that the supersonic melting of magnetic order measured with ultrafast x-rays is not the driving force of the formation of the metallic phase. We posit that the insulator metal transition may origin from the rearrangement of ordered charges at the interface propagating into the film.

cond-mat.str-el↗

arXiv2015

Optical spectroscopy and the nature of the insulating state of rare-earth nickelates

Using a combination of spectroscopic ellipsometry and DC transport measurements, we determine the temperature dependence of the optical conductivity of NdNiO$_3$ and SmNiO$_{3}$ films. The optical spectra show the appearance of a characteristic two-peak structure in the near-infrared when the material passes from the metal to the insulator phase. Dynamical mean-field theory calculations confirm this two-peak structure, and allow to identify these spectral changes and the associated changes in the electronic structure. We demonstrate that the insulating phase in these compounds and the associated characteristic two-peak structure are due to the combined effect of bond-disproportionation and Mott physics associated with half of the disproportionated sites. We also provide insights into the structure of excited states above the gap.

cond-mat.str-el↗

arXiv2015

Magneto-transport study of top- and back-gated LaAlO$_3$/SrTiO$_3$ heterostructures

We report a detailed analysis of magneto-transport properties of top- and back-gated LaAlO$_3$/SrTiO$_3$ heterostructures. Efficient modulation in magneto-resistance, carrier density, and mobility of the two-dimensional electron liquid present at the interface is achieved by sweeping top and back gate voltages. Analyzing those changes with respect to the carrier density tuning, we observe that the back gate strongly modifies the electron mobility while the top gate mainly varies the carrier density. The evolution of the spin-orbit interaction is also followed as a function of top and back gating.

cond-mat.str-el↗

arXiv2015

Spatially resolved ultrafast magnetic dynamics launched at a complex-oxide hetero-interface

Static strain in complex oxide heterostructures has been extensively used to engineer electronic and magnetic properties at equilibrium. In the same spirit, deformations of the crystal lattice with light may be used to achieve functional control across hetero-interfaces dynamically. Here, by exciting large amplitude infrared-active vibrations in a LaAlO3 substrate we induce magnetic order melting in a NdNiO3 film across a hetero-interface. Femtosecond Resonant Soft X-ray Diffraction is used to determine the spatial and temporal evolution of the magnetic disordering. We observe a magnetic melt front that grows from the substrate interface into the film, at a speed that suggests electronically driven propagation. Light control and ultrafast phase front propagation at hetero-interfaces may lead to new opportunities in optomagnetism, for example by driving domain wall motion to transport information across suitably designed devices.

cond-mat.str-el↗

arXiv2015

Tailoring the electronic transitions of NdNiO_3 films through (111)_pc oriented interfaces

Bulk NdNiO_3 and thin films grown along the pseudocubic (001)_pc axis display a 1st order metal to insulator transition (MIT) together with a Néel transition at T=200K. Here, we show that for NdNiO3 films deposited on (111)_pc NdGaO_3 the MIT occurs at T=335K and the Néel transition at T=230 K. By comparing transport and magnetic properties of layers grown on substrates with different symmetries and lattice parameters, we demonstrate a particularly large tuning when the epitaxy is realized on (111)_pc surfaces. We attribute this effect to the specific lattice matching conditions imposed along this direction when using orthorhombic substrates.

cond-mat.str-el↗

arXiv2015

Electronic Transitions in Strained SmNiO_3 Thin Films

Nickelates are known for their metal to insulator transition (MIT) and an unusual magnetic ordering, occurring at T=T_Néel. Here, we investigate thin films of SmNiO_3 subjected to different levels of epitaxial strain. We find that the original bulk behavior (T_Néel<T_MI) is strongly affected by applying compressive strain to the films. For small compressive strains, a regime where T_Néel=T_MI is achieved, the paramagnetic insulating phase characteristic of the bulk compound is suppressed and the MIT becomes 1st order. Further increasing the in-plane compression of the SmNiO_3 lattice leads to the stabilization of a single metallic paramagnetic phase.

cond-mat.str-el↗

arXiv2015

Giant Oscillating Thermopower at Oxide Interfaces

Understanding the nature of charge carriers at the LaAlO3/SrTiO3 interface is one of the major open issues in the full comprehension of the charge confinement phenomenon in oxide heterostructures. Here, we investigate thermopower to study the electronic structure in LaAlO3/SrTiO3 at low temperature as a function of gate field. In particular, under large negative gate voltage, corresponding to the strongly depleted charge density regime, thermopower displays record-high negative values of the order of 10^4 - 10^5 microV/K, oscillating at regular intervals as a function of the gate voltage. The huge thermopower magnitude can be attributed to the phonon-drag contribution, while the oscillations map the progressive depletion and the Fermi level descent across a dense array of localized states lying at the bottom of the Ti 3d conduction band. This study is the first direct evidence of a localized Anderson tail in the two-dimensional (2D) electron liquid at the LaAlO3/SrTiO3 interface.

cond-mat.str-el↗

arXiv2015

Growth-induced electron mobility enhancement at the LaAlO$_3$/SrTiO$_3$ interface

We have studied the electronic properties of the 2D electron liquid present at the LaAlO$_3$/SrTiO$_3$ interface in series of samples prepared at different growth temperatures. We observe that interfaces fabricated at 650°C exhibit the highest low temperature mobility ($\approx 10000 \textrm{ cm}^2/\textrm{Vs}$) and the lowest sheet carrier density ($\approx 5\times 10^{12} \textrm{ cm}^{-2}$). These samples show metallic behavior and Shubnikov-de Haas oscillations in their magnetoresistance. Samples grown at higher temperatures (800-900°C) display carrier densities in the range of $\approx 2-5 \times 10^{13} \textrm{ cm}^{-2}$ and mobilities of $\approx 1000 \textrm{ cm}^2/\textrm{Vs}$ at 4K. Reducing their carrier density by field effect to $8\times 10^{12} \textrm{ cm}^{-2}$ lowers their mobilites to $\approx 50 \textrm{ cm}^2/\textrm{Vs}$ bringing the conductance to the weak-localization regime.

cond-mat.mtrl-sci↗

arXiv2015

Weak-localization and spin-orbit interaction in side-gate field effect devices at the LaAlO$_3$/SrTiO$_3$ interface

Using field effect devices with side gates, we modulate the 2 dimensional electron gas hosted at the LaAlO$_3$/SrTiO$_3$ interface to study the temperature and doping evolution of the magnetotransport. The analysis of the data reveals different transport regimes depending on the interplay between the different (elastic, inelastic, and spin-orbit) scattering times and their temperature dependencies. We find that the spin-orbit interaction strongly affects the low temperature transport in the normal state in a very large region of the phase diagram, extending beyond the superconducting dome.

cond-mat.mes-hall↗

arXiv2014

Large modulation of the Shubnikov-de Haas oscillations by the Rashba interaction at the LaAlO$_{3}$/SrTiO$_{3}$ interface

We investigate the 2-dimensional Fermi surface of high-mobility LaAlO$_3$/SrTiO$_3$ interfaces using Shubnikov-de Haas oscillations. Our analysis of the oscillation pattern underscores the key role played by the Rashba spin-orbit interaction brought about by the breaking of inversion symmetry, as well as the dominant contribution of the heavy $d_{xz}$/$d_{yz}$ orbitals on electrical transport. We furthermore bring into light the complex evolution of the oscillations with the carrier density, which is tuned by the field effect.

cond-mat.str-el↗

arXiv2013

In-plane electronic confinement in superconducting LaAlO$_3$/SrTiO$_3$ nanostructures

We describe the transport properties of mesoscopic devices based on the two dimensional electron gas (2DEG) present at the LaAlO$_3$/SrTiO$_3$ interface. Bridges with lateral dimensions down to 500~nm were realized using electron beam lithography. Their detailed characterization shows that processing and confinement do not alter the transport parameters of the 2DEG. The devices exhibit superconducting behavior tunable by electric field effect. In the normal state, we measured universal conductance fluctuations, signature of phase-coherent transport in small structures. The achievement of reliable lateral confinement of the 2DEG opens the way to the realization of quantum electronic devices at the LaAlO$_3$/SrTiO$_3$ interface.

cond-mat.supr-con↗

arXiv2012

Unusual temperature dependence of the spectral weight near the Fermi level of NdNiO3 thin films

We investigate the behavior of the spectral weight near the Fermi level of NdNiO3 thin films as a function of temperature across the metal-to-insulator transition (MIT) by means of ultraviolet photoelectron spectroscopy. The spectral weight was found to exhibit thermal hysteresis, similar to that of the dc conductivity. A detailed analysis of the temperature dependence reveals two distinct regimes of spectral loss close to the Fermi level. The temperature evolution of one regime is found to be independent from the MIT.

cond-mat.str-el↗